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stunner5000pt
Nov8-06, 03:20 PM
\tau = k_{B} T
a) Find the expression for the free energy as a function of the temperature of the system with two states - one iwth eneryg zero and one with energy \epsilon_{0}

b) From the free energy find the expressions for the energy and entropy of the system

c) Plot the average energy and the entropy as a function of tau. \tau = k_{B} T

Ok for a) wek now that
F = U - T \sigma

Partition fun ction Z = \sum_{s} \exp(-\epsilon_{s}/\tau) = 1 + \exp(-\epsilon_{0}/\tau)

so then
U = \frac{\epsilon_{0} \exp(-\epsilon_{s}/\tau)}{1 + \epsilon_{0} \exp(-\epsilon_{s}/\tau)}

but im not quite sure how to proceed with the calculation of the entropy, sigma ...

for b)
for entropy use this
\sigma = \left(\frac{\partial F}{\partial \tau}\right)_{V}

but not sure about how to find the nergy for hte system... is it simply the expression wh9ich doesnt involve tau??

I was thiking a bit more

isnt helmholtz free enryg given by simple
F- F(0) = -\tau \log Z ??