chemnoob.
Nov14-10, 05:47 PM
1. The problem statement, all variables and given/known data
Calculate the vapour pressure of H2O(g) at 298K and an overall pressure of 1 atm., using the data provided. It cannot be assumed that dHvap and dSvap are independent of temperature.
H2(g) dHcomb (298K) = -241.8kj/mol (H2(g) as a product)) Cp - 33.6
H2(g) dHcomb (298K) = -285.8kj/mol (H2(l) as a product)) Cp - 75.3
2. Relevant equations
3. The attempt at a solution
I believe I need to calculate deltaH of vaporization first then use dSvap(298) = dSvap(373)+dCpln(298/373) then use gibbs free energy?
Don't know how to get deltaH
Calculate the vapour pressure of H2O(g) at 298K and an overall pressure of 1 atm., using the data provided. It cannot be assumed that dHvap and dSvap are independent of temperature.
H2(g) dHcomb (298K) = -241.8kj/mol (H2(g) as a product)) Cp - 33.6
H2(g) dHcomb (298K) = -285.8kj/mol (H2(l) as a product)) Cp - 75.3
2. Relevant equations
3. The attempt at a solution
I believe I need to calculate deltaH of vaporization first then use dSvap(298) = dSvap(373)+dCpln(298/373) then use gibbs free energy?
Don't know how to get deltaH