Chemistry Problem- Burning Magnesium

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Homework Help Overview

The discussion revolves around a chemistry lab experiment involving the reaction of magnesium with oxygen to determine the empirical formula of the resulting compound. Participants explore the products formed during the burning of magnesium and the implications of their experimental data.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to calculate the empirical formula based on mass measurements and mole ratios, questioning the accuracy of their results and the role of distilled water in the procedure. Other participants raise concerns about the validity of the empirical formula Mg2O3 and discuss the diatomic nature of oxygen in chemical reactions.

Discussion Status

Participants are actively questioning the assumptions made in the calculations and the experimental setup. Some guidance has been offered regarding the correct interpretation of oxygen's molecular form and the implications of measurement accuracy. There are multiple interpretations being explored regarding the empirical formula and the observed mass discrepancies.

Contextual Notes

Participants note potential inaccuracies in measurements due to the quality of the measuring tools used in the experiment. There is also mention of unexpected results, such as the mass of MgO being less than the initial mass of magnesium, prompting further inquiry into the reaction process.

rasperas
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Short Question- What is the product resulted from burning magnesium?
More Detail- For a chemistry lab I had to react magnesium oxygen- and thereby find out the empirical formula. Below is the lab procedure and my work.
Procedure-
1) Heat a clean dry crucible to redness. (to prevent extraneous r/x's)
2) Allow crucible to cool and mass and record.
3) Cut a piece of Mg ribbon about 5 cm. long.
4) Measure the length of Mg and record (+_ .0001 m) mass 1.00m MG = 1.2819
5) Break the Mg ribbon into small pieces into the bottom of the crucible.
6) Set crucible on ring stand/ clay triangle.
7) Heat 7-10 minutes.
8) Check for and unreacted Mg.
9) Allow crucible contents to cool.
10) Add just enough distilled water to cover the contents in the crucible.
11) Gently heat the crucible again to dry the product.

Data
a. Mass crucible 19.29
b. length Mg .0461 M (46.1 mm)
c. mass crucible and product 19.41 g.

Analysis

Mass Mg 1.2819 x .0491 = .0591
Mass O 19.41-19.29-.0591
Mole Mg .0591 g / 24.305 = .00243 mol Mg
Mole O .06 g / 15.999 = .004 mol O
Mol Ratio .004/.00243 = 1.6 mol 0 per 1 mol Mg x 2 (b/c empirical formulas contain integers only)
Allowing for room of error I get Mg2O3. However here's the rub. Mg= charge 2+
O = charge 2-. 2 x 2 = Total charge of 4+ on Mg. 2 x 3 = total charge of 6- on O. Unablanced.

Is this answer (Mg2O3) correct or is it wrong -(too many innacurate measurments in the data).?

Out of curiosity- What is the purpose of adding distilled water and then evaporating it? The cover to the crucible was on most of the lab- but never-the-less, is this sufficient to prevent nitrogen from skewing the results by reacting with Mg?

Thanks,
Rod Aspera
 
Last edited:
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rasperas said:
Short Question- What is the product resulted from burning magnesium?

Magnesium oxyde.[itex]MgO[/itex]


rasperas said:
More Detail- For a chemistry lab I had to react magnesium oxygen- and thereby find out the empirical formula. Below is the lab procedure and my work.
Procedure-
1) Heat a clean dry crucible to redness. (to prevent extraneous r/x's)
2) Allow crucible to cool and mass and record.
3) Cut a piece of Mg ribbon about 5 cm. long.
4) Measure the length of Mg and record (+_ .0001 m) mass 1.00m MG = 1.2819
5) Break the Mg ribbon into small pieces into the bottom of the crucible.
6) Set crucible on ring stand/ clay triangle.
7) Heat 7-10 minutes.
8) Check for and unreacted Mg.
9) Allow crucible contents to cool.
10) Add just enough distilled water to cover the contents in the crucible.
11) Gently heat the crucible again to dry the product.

Data
a. Mass crucible 19.29
b. length Mg .0461 m (46.1 mm)
c. mass crucible and product 19.41 g.

Analysis

Mass Mg 1.2819 x .0491 = .0591
Mass O 19.41-19.29-.0591
Mole Mg .0591 g / 24.305 = .00243 mol Mg
Mole O .06 g / 15.999 = .004 mol O
Mol Ratio .004/.00243 = 1.6 mol 0 per 1 mol Mg x 2 (b/c empirical formulas contain integers only)
Allowing for room of error I get Mg2O3. However here's the rub. Mg= charge 2+
O = charge 2-. 2 x 2 = Total charge of 4+ on Mg. 2 x 3 = total charge of 6- on O. Unablanced.

Is this answer (Mg2O3) correct or is it wrong -(too many innacurate measurments in the data).?

Out of curiosity- What is the purpose of adding distilled water and then evaporating it? The cover to the crucible was on most of the lab- but never-the-less, is this sufficient to prevent nitrogen from skewing the results by reacting with Mg?

Thanks,
Rod Aspera


Check your numbers,again.Give units in SI:m,Kg,s.What is the linear density of Mg??Give the figure in Kgm^{-1}.
There's no such thing as
[tex]Mg_{2}O_{3}[/tex]
The mole ratio should be
2moles of Mg+1mole 0_{2}=2moles MgO.
One mole of oxigen has 32g=0.032Kg,not 16g=0.016Kg

Daniel.
 
One mole of oxigen has 32g=0.032Kg,not 16g=0.016Kg

For personal simplicity, I was just expressing oxygen as non-diatomic; everything in the problem was adjusted to allow this.

Thankyou for the help.

After thinking about the problem, I realized it is an issue of accuracy. The rulers provided by school are standard "walmart" rulers. The scales also aren't scientific quality.
 
rasperas said:
For personal simplicity, I was just expressing oxygen as non-diatomic; everything in the problem was adjusted to allow this.

Thankyou for the help.

After thinking about the problem, I realized it is an issue of accuracy. The rulers provided by school are standard "walmart" rulers. The scales also aren't scientific quality.

For "personal simplicity" means entering conflict with science.One mole of Oxigen has N_{A} molecules and that's exactly 32g,not 16g.Oxigen is diatomic,and in chemical reactions it will always enter as a diatomic molecule;only under exceptional conditions it appears monoatomic,e.g.the redox reactions involving [itex]H_{2}SO_{4},H_{2}O_{2},HNO_{3},H_{2}SO_{5}[/itex] and so on.but in this case,it is a product of reaction,not a reactant.

Daniel.

Daniel.
 
My question is alwo related to Mg burning. We did the experiment at school & after MgO was produced, we massed it. It turned out that the amount of oxygen in MgO was negative--MgO weighed less than the Mg I started out with.
I'm assuming it's because smoke was given off. But why was smoke produced & what exactly is in that smoke?
 

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