Find Error in Calculating Energy Eigenstates of Particle in Box

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SUMMARY

The discussion focuses on calculating the energy eigenstates of a particle in a box, specifically addressing the error in determining the energy for the state described by the wave function Ψ(t=0). The correct energy calculation involves applying the Hamiltonian to the state Ψ, leading to the realization that the total energy is 9E_1, not 14E_1 as initially calculated. The energy eigenstates are defined by the wave functions φ_n(x) = √(2/L)sin(nπx/L) and the energies E_n = n²π²ħ²/2mL², where n = 1, 2, 3, ...

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  • Quantum mechanics principles, specifically the concept of energy eigenstates.
  • Understanding of wave functions and their normalization.
  • Familiarity with the Hamiltonian operator and its application in quantum systems.
  • Knowledge of the particle in a box model and its associated equations.
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Students and professionals in physics, particularly those specializing in quantum mechanics, as well as anyone interested in understanding the calculations of energy eigenstates in quantum systems.

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I have a particle of mass m in a box of length L. The energy eigenstates of this particle have wave functions
[tex]\phi_{n}(x)=\sqrt{2/L}sin(n \pi x/L)[/tex]
and energies
[tex]E_n = n^{2}\pi^{2}\hbar^{2}/2mL^{2}[/tex]
where n=1, 2, 3,... At time t=0, the particle is in a state described as follows.
[tex]\Psi(t=0)=\frac{1}{\sqrt{14}}[\phi_1 + 2\phi_2 + 3\phi_3][/tex]
To find the energy for state [tex]\Psi[/tex] I did the following.
[tex]\sum_{1, 2, 3} E_n = (1^2 + 2^2 +3^2) \frac{\pi^2\hbar^2}{2mL^2}=14\frac{\pi^2\hbar^2}{2mL^2}= 14E_1[/tex]
where [tex]E_1=\frac{\pi^2\hbar^2}{2mL^2}[/tex]
I have made a mistake somewhere because the actual answer is [tex]9 E_1[/tex]. Does anyone know where my error is?
 
Last edited:
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Well just apply the Hamiltonian onto the state psi. this state is the sum of three phi-terms. So each phi-state yields :
[tex]H \phi_1 = E_1 \phi_1[/tex]
[tex]2H \phi_2 = 2E_2 \phi_2[/tex]
[tex]3H \phi_3 = 3E_3 \phi_3[/tex]

Just add up everything and you get :

[tex]H \Psi =\frac {1}{\sqrt14} (E_1 \phi_1 + 2E_2 \phi_2 + 3E_3 \phi_3)[/tex]

The clue is to write down each energy term as a function of [tex]E_1[/tex]. You have a formula given to do that. Keep in mind that the coefficients of the psi-wave-function denote the possible energy values for the system



Good Luck

marlon
 
Last edited:
Ps, as an additional question : can you give me the probability that the psi-system has energy value 9E_1 ?

regards
marlon
 

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