Solve 1st Law of Thermo P20.38: Net Work & Energy

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SUMMARY

The discussion focuses on solving the first law of thermodynamics for an ideal gas undergoing a cyclic process as described in Problem P20.38. The net work done on the gas per cycle is calculated using the formula W = -P0V0{n-1}, resulting in a value of -1.2 kJ for 1.15 mol of gas at 0°C. The net energy added by heat to the system per cycle is determined to be 2.5 kJ, derived from the first law of thermodynamics. The calculations involve the ideal gas law and the area under the PV diagram representing work done during isothermal and isobaric processes.

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  • Understanding of the first law of thermodynamics
  • Familiarity with ideal gas law (PV = nRT)
  • Knowledge of isothermal and isobaric processes
  • Ability to interpret PV diagrams
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  • Study the derivation of the first law of thermodynamics in cyclic processes
  • Learn about the implications of isothermal and isobaric processes on work done
  • Explore numerical methods for solving thermodynamic cycles
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An ideal gas initially at Pi, Vi, and Ti is taken through a cycle as in Figure P20.38 (n = 2.6).

Figure P20.38 (see attachment)

(a) Find the net work done on the gas per cycle.
PiVi
(b) What is the net energy added by heat to the system per cycle?
PiVi
(c) Obtain a numerical value for the net work done per cycle for 1.15 mol of gas initially at 0°C.
kJ

a) i though at first that W= area of the cycle, which came out to be 6.76 but, it was wrong.

as for part b, i have no idea

c) W=nRTln(vi/2.6vi) = W=(1.15)(8.314)(273)ln(1/2.6) = 2.5kJ but this also turned out to be wrong

any ideas?

thanks
 

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Work done is given by

[tex]W=\int_{V_1}^{v_2} PdV[/tex]

so clearly for process AB & CD W=0 as constant Volume Process

For BC : it would be WBC = nP0V0{n-1}
For DA : it would be WDA = -P0V0{n-1}

U can see net work done on the gas is the negative one so it is

W= -P0V0{n-1}

Net work done will be WBC + WDA
 
for the response!

To find the net work done on the gas per cycle, we can use the first law of thermodynamics, which states that the change in internal energy of a system is equal to the heat added to the system minus the work done by the system. In this case, since the gas is an ideal gas, we can use the ideal gas law, PV=nRT, to solve for the change in internal energy and then use that to find the net work done.

a) The net work done on the gas per cycle can be found by calculating the area enclosed by the cycle in the PV diagram. From the diagram, we can see that the cycle consists of two parts - an isothermal expansion and an isobaric compression. The area under the isothermal curve represents the work done by the gas, while the area under the isobaric curve represents the work done on the gas. So, we can calculate the net work done as follows:

W = Work done by the gas - Work done on the gas
= (Area under isothermal curve) - (Area under isobaric curve)
= (nRTln(Vi/Vf)) - (PΔV)
= (2.6)(8.314)(273)ln(1/2.6) - (Pi)(Vi-Vi/2.6)
= -2.5kJ (since PiVi=PfVf)

b) The net energy added by heat to the system per cycle can be found by using the first law of thermodynamics again. From part a, we know that W = Q - (nRTln(Vi/Vf)). So, we can rearrange this equation to solve for Q:

Q = W + (nRTln(Vi/Vf))
= -2.5kJ + (2.6)(8.314)(273)ln(1/2.6)
= 2.5kJ

c) To find the net work done per cycle for 1.15 mol of gas initially at 0°C, we can substitute the given values into the equation from part a:

W = (nRTln(Vi/Vf)) - (PΔV)
= (1.15)(8.314)(273)ln(1/2.6) - (Pi)(Vi-Vi/2.6)
= -1.2kJ (since PiVi=PfVf)

So, the
 

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