Vapour Pressure: Pressure Exerted on Liquid & Container

In summary, vapour pressure is the pressure of a vapor in thermodynamic equilibrium with its condensed phases in a closed system. This means that the pressure exerted by the vapor on the container is the same as the pressure exerted on the liquid, according to Pascal's law. This pressure is also known as the "pressure of saturated vapor" and can be found in tables based on the temperature and curvature of the liquid surface. However, if the container is at a higher altitude, the pressure would be lower due to gravity, as explained by the barometric formula.
  • #1
johnathon
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According to Wikipedia, vapour pressure is the pressure of a vapor in thermodynamic equilibrium with its condensed phases in a closed system.
Does that mean the pressure the vapour exerts on the container or the pressure the vapour exerts on the liquid?
 
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  • #2
Jonathon,
if we compare the pressure of saturated vapor on the container at the level of the liquid and the pressure on the liquid, these are the same, by Pascal's law - in fluids, static pressure is the same in all directions. This is the pressure given as "pressure of saturated vapor" in tables (depends on the temperature and the curvature of liquid surface).

If the pressure on the container was considered at higher altitude, this would be lower due to gravity (look for barometric formula).

Jano
 

1. What is vapour pressure?

Vapour pressure is the pressure exerted by the gaseous form of a liquid when the two are in equilibrium. It is a measure of the tendency of a liquid to evaporate into its gas phase.

2. How is vapour pressure determined?

Vapour pressure is determined by factors such as temperature, intermolecular forces, and the properties of the liquid and its container. It can be calculated using various equations, such as the Clausius-Clapeyron equation.

3. Why is vapour pressure important?

Vapour pressure is important in many scientific and industrial processes. It is used to predict and control the evaporation rate of liquids, and is also a crucial factor in determining the boiling point of a substance.

4. How does vapour pressure affect the properties of a liquid?

Vapour pressure is directly related to the volatility, or tendency to evaporate, of a liquid. A higher vapour pressure means a more volatile liquid, while a lower vapour pressure means a less volatile liquid. Vapour pressure also affects the boiling point, surface tension, and other properties of a liquid.

5. Can vapour pressure be changed?

Yes, vapour pressure can be changed by altering the temperature, pressure, or composition of the system. For example, increasing the temperature will increase the vapour pressure, while adding a non-volatile solute will lower the vapour pressure of a liquid.

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