What Force Causes Electron Orbitals?

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Discussion Overview

The discussion centers around the forces that govern electron orbitals in atoms, exploring the nature of electron-nucleus interactions, the role of kinetic energy, and the implications of quantum mechanics. Participants delve into concepts related to electrostatic forces, angular momentum, and the uncertainty principle, while also addressing the shapes of electron orbitals.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • Some participants suggest that kinetic energy is a key factor preventing electrons from falling into the nucleus, comparing it to the Moon's orbit around Earth.
  • Others argue that the electrostatic force between the positively charged nucleus and negatively charged electrons keeps the electrons bound, but question why electrons do not simply collapse into the nucleus.
  • A participant mentions that at the quantum level, electrons cannot be treated as classical objects, and their behavior is better described by probability waves and the uncertainty principle.
  • There is a discussion about the shapes of electron orbitals, with participants describing the spherical nature of s orbitals, the dumbbell shape of p orbitals, and the more complex shapes of d and f orbitals.
  • Some participants express confusion about how the uncertainty principle relates to electron behavior and the concept of an electron cloud around the nucleus.
  • One participant highlights that electrons can only change energy states by emitting photons, which relates to their quantized nature.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the exact mechanisms governing electron orbitals, with multiple competing views and interpretations of quantum mechanics presented throughout the discussion.

Contextual Notes

There are limitations in the discussion regarding the assumptions made about classical versus quantum descriptions of atomic behavior, and the implications of the uncertainty principle are not fully resolved.

Who May Find This Useful

This discussion may be of interest to individuals studying atomic physics, quantum mechanics, or those curious about the fundamental nature of matter and electron behavior in atoms.

hexhunter
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which force separates the electrons and nucleus and causes the electrons to orbit?

a friend told me that the size of the electron means that the nuclei cannot absorb it, but i am still confused and not sure if he knew what i meant in my question.
 
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The same reason why the Moon does not fall on Earth: kinetic energy!
 
SGT said:
The same reason why the Moon does not fall on Earth: kinetic energy!

That's sort of partly true, but not exactly. Really, the properties that will tell you whether an orbiting object will crash into that which it's orbiting are both the angular momentum and energy. The moon could have the same kinetic energy and distance, but still crash into the Earth if its angular momentum were small. These arguments don't really apply to electrons around nuclei, though, so I don't think it answers the OP's question.

The most straightforward answer to the question is that the electrostatic force keeps the electron bound to the nucleus. Is that what you're looking for, hexhunter?
 
i understand that EM stops it from running away, but as the nucleus is +ve and the electron -ve, there is no possibility in my mind that the wouldn't just sink straight into the nucleus, unless if it is just chance that when the nuclei and electrons met, that the electrons where quickly enough forced into the neuclei at their conceivment to make orbit around the nucleus without the EM being too powerful for the electrons to avoid.

though any theory like this would surely suggest that all atoms will neutralise, or do whatever is meant to happen in this event, like a time bomb, not like any of the other 'end of the universe' theories that i have heard of...
 
Remember that at the quantum level, there's no friction, gravity, air resitance, etc. to impede it's momentum. Also, it can only reduce it's orbit in discrete steps. In order to move closer to the nucleus, the electron has to spit out a photon to drop into the next energy state (orbital).
 
What your friend was probably talking about was that the nulceus is too small to contain an electron from a quantum perspective.

A nucleus is an extremely tiny thing (diameter aprox 10^18cm), and if there was an electron inside it then we would know its location almost exactly. According to the uncertainty principle, the electron would then have a very large (but uncertain) kinetic energy, which would cause it to break out of the nucleus. So electrons reach a compromise, depending on their energy they orbit the nucleus in shells of "surface area" dictated by this rule.
 
i understand that EM stops it from running away, but as the nucleus is +ve and the electron -ve, there is no possibility in my mind that the wouldn't just sink straight into the nucleus

here is what you sound like:

"i understand that gravity holds the Earth to the sun, but since gravity is attractive, there is no possibility in my mind that the Earth wouldn't just sink straight into the sun".

Think of swinging a pail above your head. The pail is orbitting you, and you are holding it by a rope. The only force you exert on the pail to make it orbit you, is pulling the rope in towards yourself!
 
so the Kinetic energy of the electron is enough to avoid the EM attraction, but keep the orbit, and the electron will never slow, because of the vacuum? but while there is no gravity, there still is the EM from the interaction between the charges.

also, is the orbit round?
 
hexhunter said:
also, is the orbit round?

acording, are you talking about the electrons in the s, p, d, or f orbits
The ones in the s orbit are spherical
the p are kinda dumbell shaped
the d are two dumbell crossing at X,Y,or Z axis besides the d5 (5 should be subsized) which is a dumbell with a ring aroud it :confused: (that is what the textbook showed)
the f are for the most part 3 dumbell, but there are some weird ones as well
 
  • #10
locke said:
A nucleus is an extremely tiny thing (diameter aprox 10^18cm), and if there was an electron inside it then we would know its location almost exactly. According to the uncertainty principle, the electron would then have a very large (but uncertain) kinetic energy, which would cause it to break out of the nucleus.

:up:
:approve:
that's it!

however one difficulty in this is that it is sometimes hard to understand how the uncertaincy principle can force an electron to behave in this or that way...
 
  • #11
hexhunter said:
so the Kinetic energy of the electron is enough to avoid the EM attraction, but keep the orbit, and the electron will never slow, because of the vacuum? but while there is no gravity, there still is the EM from the interaction between the charges.

Alright, there seem to be two points of confusion here, one classical and one quantum. If we could treat atoms as mini solar systems then Crosson's explanation would end the story. That is, the electron would be pulled inwards by the attraction of the proton, but by Newton's first law, its momentum would want to keep carrying it in some other direction. Some balance would be achieved between these two effects that would allow the electron to continue in an orbit around the nucleus, just as happens with the planets around the sun.

However, this is not a good description of atoms. It turns out that, at these scales, the laws of quantum mechanics begin to become apparent and the electron begins to behave in ways that make no sense in the description I gave above. For this, locke gave a good answer. The electron cannot be treated as a simple object with definite position and momentum, but instead as a sort of probability wave that can exist in a series of states. These were partially described by lawtonfogle.
 
  • #12
SpaceTiger said:
For this, locke gave a good answer. The electron cannot be treated as a simple object with definite position and momentum, but instead as a sort of probability wave that can exist in a series of states.
Yeah. I learned to consider the area around the nucleus as an electron orbital cloud. A haze of varying probabilities, and somewhere in that cloud the probability of an electron being there is high enough that it really is.
 
  • #13
Danger said:
A haze of varying probabilities, and somewhere in that cloud the probability of an electron being there is high enough that it really is.

Keep in mind that the "cloud" and the probability distribution function are one and the same. Your description is a sort of semi-classical way of thinking about it, but I think the Copenhagen interpretation implies that the probability "cloud" is the most fundamental physical reality.
 
  • #14
SpaceTiger said:
Keep in mind that the "cloud" and the probability distribution function are one and the same. Your description is a sort of semi-classical way of thinking about it, but I think the Copenhagen interpretation implies that the probability "cloud" is the most fundamental physical reality.
Yeah, that's what I meant. Bad choice of phrasing on my part. I'm used to dealing with people who have no knowledge of science whatsoever, so I sometimes translate sloppily.
 
  • #15


SpaceTiger said:
the Copenhagen interpretation implies that the probability "cloud" is the most fundamental physical reality.

Correct me if I sound dumb, but the 'most fundamental physical reality' is uncertainty?
 

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