Lattice Energy and the Born Haber Cycle

In summary, when dealing with the Born Haber Cycle, there are several factors that need to be considered, such as sublimation energy, dissociation energy, electron affinity, ionization energy, and formation energy. To calculate the formation energy, the formula Hf= Hs+Hi.e.+1/2Hd+He.a.+U (lattice energy) is used. However, if all values except for the lattice energy are known, the lattice energy can be calculated using the formula provided in the link provided by the conversation partner.
  • #1
President Mercury
19
0
Ok most questions (that I have come across) when dealing with the Born Haber Cycle give the Sublimation energy, the Dissociation energy, the Electron Affinity, the Ionization Energy, and the Formation Energy. I know that to get the Formation Energy it is:

Hf= Hs+Hi.e.+1/2Hd+He.a.+U (Lattice Energy)

My problem is that if everything but the lattice energy is given what is the calculations to get the lattice energy. I know the lattice energy for some examples like NaCl but that's just from memory, I just don't know how to get the lattice energy (assuming that I didn't memorize it) by using a calculation. Can anyone shed some light on this for me? Would be much appreciated.
 
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  • #2
Try here. I googled it... "lattice energy calculation".

http://www.science.uwaterloo.ca/~cchieh/cact/applychem/lattice.html
 
  • #3
Thank you. I guess I couldn't find it since I didn't simply put "calculation" at the end of my search.
 

1. What is lattice energy?

Lattice energy is the measure of the strength of the electrostatic forces between ions in an ionic compound. It is the energy released when one mole of an ionic crystal is formed from its gaseous ions.

2. How is lattice energy calculated?

Lattice energy is calculated using the Born-Haber cycle, which takes into account the various energy changes involved in the formation of an ionic compound, such as ionization energy, electron affinity, and enthalpy of formation.

3. How does lattice energy affect the properties of ionic compounds?

The magnitude of lattice energy determines the stability and melting point of an ionic compound. Higher lattice energy results in a more stable compound with a higher melting point.

4. What factors affect lattice energy?

The main factors that affect lattice energy are the charges of the ions, the distance between the ions, and the size of the ions. As the charges increase and the distance between ions decreases, the lattice energy also increases.

5. Can lattice energy be measured experimentally?

No, lattice energy cannot be measured directly. It is a calculated value based on theoretical calculations using the Born-Haber cycle. However, enthalpy changes involved in the process can be measured experimentally and used to calculate the lattice energy.

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