Overlap integrals and eigenstates problem

In summary, the probability of a particle being at position x is determined by taking the square of the wave function. In the case of finding the probability of a wave function being in eigenstate n, we use the overlap integral of the wave function and normalised eigenstate. This is because the overlap is the probability amplitude which is complex, and in order to find the probability, we need a real value which is achieved by squaring the overlap.
  • #1
randybryan
52
0
To find the probability of a particle being at position x we use

<[tex]\Psi[/tex]|[tex]\Psi[/tex]> where the complex conjugate ensures that the answer is real. This means that we're looking at the square of the wave function to determine the probability of finding the particle.

Now to determine the probability of a wave function being in eigenstate n, we use the overlap integral of the wave function and normalised eigenstate (for general harmonic oscillator potential V(x) = 1/2m[tex]\omega[/tex]^{2}x^{2}) over all x. Now I don't understand why we take the square of this answer to find the probability? I know we're not looking for the probability of a position, but an energy eigenstate. I just can't follow where it comes from.
Apologies for not writing out the equation, but the Latex is screwing up for me
 
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  • #2
We DO take the square of the overlap to find the probability, in either case. The overlap is called the probability amplitude, which in general is complex, whereas a probability must be real.

In your first case, Ψ(x) (or <x|Ψ>) is the probability amplitude and Ψ*(x)Ψ(x) or <Ψ|x><x|Ψ> is the probability of finding the particle at point x. Your second case is exactly the same, except it's <n|Ψ> instead of <x|Ψ>.
 
  • #3
Thanks! :)
 

1. What are overlap integrals and why are they important?

Overlap integrals are mathematical calculations used in quantum mechanics to determine the degree of overlap between two quantum states. They are important because they provide information about the similarity or difference between two states, which is crucial for understanding the behavior of quantum systems.

2. How do overlap integrals relate to the eigenstates problem?

Overlap integrals are used in the eigenstates problem to determine the coefficients of a linear combination of eigenstates that will produce a specific quantum state. This allows us to express a quantum state as a combination of simpler, more easily understood eigenstates.

3. What is the formula for calculating overlap integrals?

The formula for calculating overlap integrals is given by ∫ψ1*(r)ψ2(r)dr, where ψ1 and ψ2 are the two quantum states in question and r represents the position in space.

4. Can overlap integrals be negative?

Yes, overlap integrals can be negative. This indicates that the two quantum states have opposite phases, which means they interfere destructively. In other words, the two states cancel each other out and result in a net zero probability of finding the particle in that region of space.

5. What is the significance of a large overlap integral?

A large overlap integral indicates a high degree of similarity between two quantum states. This means that the two states have similar energy levels and are likely to interact with each other, which can have important implications for the behavior of the system as a whole.

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