Reaction between propanone and iodine

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In summary, the rate determining step of the reaction between propanone and iodine in acidic medium is the first step, which involves the polarization of the pi-bond in C=O by iodine. This indicates that iodine does indeed play a role in the rate determining step and is considered a catalyst in this reaction. The second step, involving the attachment of protons to polarized O atoms, is a fast step and therefore not relevant in the rate law.
  • #1
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Homework Statement


Does iodine take part in the rate determining step of reaction between propanone and iodine in acidic medium?

Homework Equations


The Attempt at a Solution


For positive catalyst the rate determining step is the 1st step of the at least 2 steps of reactions after being catalysed(usually??).
Since the reaction is order 1 with respect to iodine and also to hydrogen ions and 0th order to propanone, and the 1st step should be the reaction between the catalyst and 1 of the reactants, it should be between iodine and hydrogen ions because iodine controls the rate of the reaction and so it is 'rate determining' and take part in the r.d.s.

Are the hydrogen ions catalyst of the reaction? If so how do they act as the catalyst?? I mean are there like substeps with high reaction rates or it's about something else like adsorption to ions??
How would I know whether it takes part in the rate determining step or not?
What should be the answer actually?
I am highly uncertain about my assumptions in the above deduction, please correct me also!
 
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  • #2
Clear up some misconceptions first.

Catalyst - A reactant which speeds up/down the reaction rate by affecting the formation of intermediate product or altering the reaction mechanism, and is recovered at the end of reaction, so catalyst isn't technically a reactant in the overall reaction.

The reaction of acetone with Iodine is Nucleophilic addition. In the 1st step, which is also the RDS, the pi-bond in C=O polarizes towards O atom, creating valency vacancy on C atom. Nucleophile attacks on the C atom and forms Tetrahedral intermediate.

Now note that polarization of pi-bond depends upon the attacking electrophile, so Iodine is involved in R.D.S.

In the second step, protons are attached to polarized O atoms, then you get your compound. It is a fast step, thus not serving relevance in rate law.
 

What is the reaction between propanone and iodine?

The reaction between propanone and iodine is an oxidation reaction that results in the formation of iodoform. Propanone (also known as acetone) is a ketone compound with the chemical formula C3H6O, while iodine is a halogen element with the chemical symbol I. When these two substances react in the presence of an oxidizing agent, such as potassium hydroxide, the iodine is reduced to form iodoform (CHI3) and propanone is oxidized to form acetic acid (CH3COOH).

What are the products of the reaction between propanone and iodine?

The products of the reaction between propanone and iodine are iodoform (CHI3) and acetic acid (CH3COOH). The reaction can also produce small amounts of other by-products, such as carbon dioxide and water.

What are some common uses of the reaction between propanone and iodine?

The reaction between propanone and iodine is commonly used in organic chemistry laboratories to demonstrate oxidation-reduction reactions. It is also used in the production of iodoform, which has antiseptic properties and is used in some medical procedures. Additionally, this reaction is used in the synthesis of various organic compounds, such as pharmaceuticals and plastics.

What are the conditions required for the reaction between propanone and iodine to occur?

The reaction between propanone and iodine requires the presence of an oxidizing agent, such as potassium hydroxide, and a neutral or slightly acidic medium. It also requires heat to initiate the reaction and speed up the reaction rate. The reaction can be carried out at room temperature, but it may take longer to complete.

What safety precautions should be taken when performing the reaction between propanone and iodine?

When performing the reaction between propanone and iodine, it is important to wear appropriate protective equipment, such as gloves and safety goggles, to avoid contact with the chemicals. The reaction should also be carried out in a well-ventilated area, as it may produce harmful fumes. Any spills or accidents should be cleaned up immediately and the chemicals should be disposed of properly according to laboratory safety guidelines.

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