What causes the H bonds in water molecules to last only 10^-11 sec?

In summary, the conversation discusses two possible explanations for the short duration of hydrogen bonds in water molecules. The first explanation suggests that there is a constant equilibrium in the system, where some water molecules form and break hydrogen bonds, while the second explanation points to the constant movement and changing electron density of water molecules as the cause for the short lifespan of hydrogen bonds. It is unclear which explanation is correct, if any.
  • #1
scientiavore
6
0
I have thought of two possible explanations:

a) Energy required to break H bonds = Energy released when H bonds form.
There is a "constant" equilibrium in the system, meaning, some water molecules form H bonds, releasing energy to the environment which causes other water molecules to loose their H bonds, and this could on forever if isolated.

b) The H bonds last so little because the e- density in the water molecules change, the partially charged zones of the molecule are not constant and they change over time breaking the H bonds between the water molecules.

Which one is correct(if any)?
 
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  • #2
i would suggest that it is because the water molecules are constantly moving around because they possesses kinetic energy.
 
  • #3


Both explanations have some validity in explaining the short lifespan of H bonds in water molecules. However, the most accurate explanation is likely a combination of both factors.

The first explanation, based on energy equilibrium, is correct in that the energy required to break H bonds is indeed similar to the energy released when they form. This means that the bonds are relatively weak and can easily be broken and reformed. However, this explanation does not take into account the constant movement and rearrangement of water molecules in solution.

The second explanation, based on the changing electron density of water molecules, is also valid. As water molecules move and interact with each other, the distribution of electrons within the molecule can change, leading to a weakening or breaking of H bonds. This is due to the polar nature of water and the constant movement of its molecules.

In reality, the short lifespan of H bonds in water molecules is a result of both factors. The weak nature of the bonds and the constant movement and rearrangement of water molecules work together to ensure that H bonds only last for a very short period of time (10^-11 seconds). This allows for the dynamic nature of water and its ability to form and break bonds, which is essential for many biological processes.
 

1. What are hydrogen bonds and why are they important in water molecules?

Hydrogen bonds are weak electrostatic attractions between a hydrogen atom in one molecule and an electronegative atom in another molecule. In water molecules, the hydrogen bonds between oxygen and hydrogen atoms help to bind the molecules together, giving water its unique properties such as high surface tension and ability to dissolve many substances.

2. What factors contribute to the short lifespan of hydrogen bonds in water molecules?

The short lifespan of hydrogen bonds in water molecules is primarily due to the constant motion and collisions of water molecules. As water molecules move and collide, the hydrogen bonds are continuously broken and reformed, resulting in an average lifespan of only 10^-11 seconds.

3. Can the lifespan of hydrogen bonds in water molecules be extended?

While it is not possible to extend the lifespan of individual hydrogen bonds in water molecules, it is possible to increase the overall strength of hydrogen bonding in a system by increasing the concentration of hydrogen bonds. This is often seen in solutions with higher concentrations of solutes, where the increased number of hydrogen bonds between water molecules leads to a stronger overall bond network.

4. How do temperature and pressure affect the lifespan of hydrogen bonds in water molecules?

Higher temperatures and pressures can disrupt hydrogen bonding in water molecules, leading to a shorter lifespan. This is because the increased kinetic energy and molecular movement at higher temperatures and pressures can break the relatively weak hydrogen bonds more easily. On the other hand, lower temperatures and pressures can promote stronger hydrogen bonding and lead to a longer lifespan.

5. Are there any other factors that can influence the lifespan of hydrogen bonds in water molecules?

Yes, the presence of other molecules or ions in the surrounding environment can also affect the lifespan of hydrogen bonds in water molecules. For example, polar molecules can compete for hydrogen bonding with water molecules, potentially disrupting the bond network. Additionally, the pH of a solution can also affect the strength and lifespan of hydrogen bonding in water molecules.

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