E=1/n^2 (-13.6eV) for other one-electron atoms –ionized helium (Z=2),

In summary, the value of -13.6eV is significant as it represents the energy of the ground state of the simplest one-electron atom, hydrogen, and is used as a reference point for calculating the energy of other one-electron atoms. The energy of one-electron atoms is inversely proportional to the square of the principal quantum number due to the relationship between the distance of the electron from the nucleus and its energy. The value of Z (atomic number) affects the energy of one-electron atoms by increasing the strength of the attractive force between the electron and nucleus. This formula is not applicable to multi-electron atoms. The energy of ionized helium is four times greater than that of the hydrogen atom due to the stronger attractive
  • #1
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E=1/n^2 (-13.6eV) for other one-electron atoms –ionized helium (Z=2), doubly-ionized lithium (Z=3),etc. I found contradicting here is that one-electron atom and Z=2, 3. If it’s one electron, then there is only one proton, so where do 2 or 3 protons come from?
Thanks.
 
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  • #2


Umm...doubly ionized Lithium is missing two of it's electrons. Hence it has one electron and three protons. That's why it is IONized.
 
  • #3


I can understand your confusion with the concept of one-electron atoms and their ionization states. Let me clarify this for you.

When we say one-electron atom, we are referring to the number of electrons present in the atom. In this case, it means that there is only one electron orbiting around the nucleus. However, the number of protons in the nucleus can vary. For example, hydrogen has one electron and one proton, while helium has one electron and two protons. This is why helium is considered a one-electron atom.

Now, when we talk about ionization, we are referring to the process of removing one or more electrons from an atom. This can be done by supplying energy to the atom, which causes the electron to jump to a higher energy level or completely leave the atom. In the case of helium (Z=2), it can be ionized to become a doubly-ionized atom (Z=2+2=4) by removing both its electrons.

Similarly, lithium (Z=3) can also be ionized to become a doubly-ionized atom (Z=3+2=5) by removing both its electrons. So, the number of protons in the nucleus does not necessarily match the number of electrons in the atom.

I hope this explanation helps to clear up any confusion. As scientists, we must always question and seek to understand the concepts we come across. Keep up the curious mindset!
 

1. What is the significance of the value -13.6eV in the formula for the energy of one-electron atoms?

The value of -13.6eV represents the energy of the ground state of the hydrogen atom, which is the simplest one-electron atom. This value is used as a reference point for calculating the energy of other one-electron atoms.

2. Why is the energy of one-electron atoms inversely proportional to the square of the principal quantum number (n)?

This is due to the relationship between the distance of the electron from the nucleus and its energy. As the principal quantum number increases, the distance between the electron and nucleus increases, resulting in a decrease in the attractive force between them and, therefore, a decrease in the energy of the electron.

3. How does the value of Z (atomic number) affect the energy of one-electron atoms?

The value of Z affects the energy of one-electron atoms by increasing the strength of the attractive force between the electron and nucleus. This leads to a decrease in the energy of the electron, as it is held more tightly by the nucleus.

4. Can the formula for the energy of one-electron atoms be applied to other multi-electron atoms?

No, the formula for the energy of one-electron atoms is only applicable to atoms with a single electron. For multi-electron atoms, the energy levels are more complex and cannot be described by a simple formula.

5. How does the energy of ionized helium compare to that of the hydrogen atom?

The energy of ionized helium (Z=2) will be four times greater than the energy of the hydrogen atom, as there are now two protons in the nucleus, resulting in a stronger attractive force on the single electron. This means that it will take four times more energy to completely remove the electron from the ionized helium atom compared to the hydrogen atom.

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