Thickness of oxidation layer on fuel elements.

In summary, the acceptable limit on the thickness of the oxidation layer on Zircaloy4 fuel rods is generally stated to be 100 micrometers. This limit is mainly about structural integrity and thermal resistance, as it affects the cladding temperature. It is also somewhat arbitrary and has been studied extensively in recent years due to concerns about the response of the cladding to RIA transients and LOCA events. The oxide thickness is used as a measure of hydrogen absorption, which can embrittle the zirconium. Non-destructive measurements, such as eddy-current liftoff probes, can be used to measure the oxide thickness. However, these measurements must be corrected for the magnetic susceptibility of any crud on the oxide layer. In
  • #1
vanesch
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I have a question: it is generally stated that 100 micrometers is the acceptable limit on the thickness of the oxidation layer on Zircaloy4 fuel rods. But I'm at loss as what is the reason for this limit ? Is it structural integrity ? Thermal resistance ? Mechanical tolerance ?
 
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  • #2
I've never really heard of a limit on ZrO2 layer, so my input is just for conversation.

A little oxide layer is a good thing: prevents the zirconium steam reaction at elevated sheath temps.

but like you say, if too much Zr is oxididized, it would be brittle with poor heat transfer.
 
  • #3
vanesch said:
I have a question: it is generally stated that 100 micrometers is the acceptable limit on the thickness of the oxidation layer on Zircaloy4 fuel rods. But I'm at loss as what is the reason for this limit ? Is it structural integrity ? Thermal resistance ? Mechanical tolerance ?
It's mainly about structural integrity, but it's also about thermal resistance as it effects the cladding temperature, which affects structural integrity if rod internal pressure exceeds critical limit (lift-off).

That limit is somewhat arbitrary, and has received a lot of study in the last decade as a result of two concerns - 1) the response of the cladding to RIA transients and 2) response of cladding to LOCA and subsequent quenching when cooler water is introduced to the core.

Way back in the good old days, Westinghouse set limit of 100 microns which was calculated to yield an average value of 600 ppm H in the cladding wall. That value is based upon a hydrogen pickup rate (~0.15 - 0.17) during the course of operation. The actual H-pickup ratio is highly variable and has dependence on water/oxide chemistry. Hydrogen embrittlement is an issue at low temperatures.

In the past 15 years, there has also been increased attention to the spallation of cladding oxide, which can result in local cool areas on the cladding with the result the hydrogen migrates from the surronding area to the cooler area. Significant hydrogen (1000-3000 ppm), and this could present a problem for structural integrity under certain off-normal conditions (e.g. RIA) and potentially at high burnup during a power increase (e.g. so-called 'out-to-in' failures).

Westinghouse has developed ZIRLO (Zr-Nb-Sn-Fe) alloy and AREVA has developed M5 (Zr-Nb-O) alloy in order to reduce both the oxide thickness and hydrogen pickup as a function of burnup (exposure).
 
  • #4
Ah, so the oxide thickness is taken as a kind of rough measure of hydrogen absorption (which embrittles zirconium, I know). It is not the oxide layer itself which is the main difficulty, but rather the (more difficult to measure) hydrogen intake, but as both are correlated, we put a limit on the easiest observable one, is that it ?
 
  • #5
vanesch said:
Ah, so the oxide thickness is taken as a kind of rough measure of hydrogen absorption (which embrittles zirconium, I know). It is not the oxide layer itself which is the main difficulty, but rather the (more difficult to measure) hydrogen intake, but as both are correlated, we put a limit on the easiest observable one, is that it ?
Correct. One can measure the oxide thickness non-destructively, usually with an eddy-current liftoff probe, which is correlated to oxide thickness, as opposed to destructive testing where hydrogen is measured by metallography or hot-extraction (e.g. LECO test).

Eddy-current liftoff measurements must be corrected for the magnetic susceptibility Ipermeability) of the crud on the oxide layer. This has been an issue in plants which use Zn-injection in the primary cooling system. It was first noticed in BWRs, but now that PWRs are using Zn-injection, it is also an issue there.

Helmut Fischer GmbH makes thickness probes -
http://www.helmut-fischer.com/indexCountry.asp?CountryID=29&LanguageID=6

There is also the loss of the metal (structure). ZrO2/Zr has a Pilling-Bedworth ratio of about 1.56, so there is that issue to consider in conjunction with the hydrogen.

In high burnup fuel, one may find hydrogen accumulation in the outer surface of the cladding wall, particularly in the region of the cladding adjacent to the pellet-pellet interfaces. It is the localization of hydrogen that is of concern, since that potentially may be the weakest point.

This might be of use (it's dated but informative) -

Waterside Corrosion of Zirconium Alloys in Nuclear Power Plants
IAEA TECDOC Series No. 996
http://www-pub.iaea.org/MTCD/publications/PDF/te_996_web.pdf (22.3 MB - use 'save target as')
1998.
 
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  • #6
Astronuc said:
I high burnup fuel, one may find hydrogen accumulation in the outer surface of the cladding wall, particularly in the region of the cladding adjacent to the pellet-pellet interfaces. It is the localization of hydrogen that is of concern, since that potentially may be the weakest point.

Yes, I remember that somewhere: it is due to the slightly lower temperature and a preferred migration of the hydrogen towards the cooler regions, no ?

This might be of use (it's dated but informative) -

Waterside Corrosion of Zirconium Alloys in Nuclear Power Plants
IAEA TECDOC Series No. 996
http://www-pub.iaea.org/MTCD/publications/PDF/te_996_web.pdf (22.3 MB - use 'save target as')
1998.

Wow! The "everything you wanted to know about zirconium but didn't dare to ask" volume :smile: :bugeye:

Thanks a lot!
 
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  • #7
Yes, hydrogen migrates from the hotter regions to the cooler regions where it precipitates as ZrH2, Zr hydride, which while it acts like a matrix stiffener (like a whisker with a high modulus), it also gives rise to local stresses. Furthermore, the migration of H through the metal leaves a high concentration of dislocations, which IMO can promote crack nucleation under the right conditions.

TECDOC 996 is a great overview of the state of the art in 1998. I know most of the people who co-authored that document and who are cited within.

We actually need an update since there has been a lot of work in the last decade on the subject.
 
  • #8
Astronuc said:
Furthermore, the migration of H through the metal leaves a high concentration of dislocations, which IMO can promote crack nucleation under the right conditions.

as an aside, that sounds a bit like the method thru which 'delayed hydride cracking' can occur in Zr pressure tubes. As the unit comes down below 200 degrees C or so, the hydrogen which has migrated to cool/high stress areas comes out of solution leaving Zr hydride platelets, which are brittle, and will crack from the process pressure in the tube. This crack acts as a stress riser, attracting more hydride on the next cool down cycle.
 
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  • #9
Homer Simpson said:
as an aside, that sounds a bit like the method thru which 'delayed hydride cracking' can occur in Zr pressure tubes. As the unit comes down below 200 degrees C or so, the hydrogen which has migrated to cool/high stress areas comes out of solution leaving Zr hydride platelets, which are brittle, and will crack from the process pressure in the tube. This crack acts as a stress riser, attracting more hydride on the next cool down cycle.
It's the cycling of temperature, which drives the cycle of solution and precipitation (or resolution/re-precipitation) of the hydrides that drives DHC (delayed hydride cracking). Even though the Zr-Nb (or Zr-2) pressure tubes have low oxide thickness, they have a relatively large surface area, and IIRC it was the cold (inlet) end that had the DHC.

There is a similar mechanism in failed fuel, which is more of a HACP (hydrogen-assisted crack propagation).
 

1. What is the purpose of measuring the thickness of oxidation layer on fuel elements?

The thickness of oxidation layer on fuel elements is an important factor to consider in nuclear fuel management. It directly affects the performance and lifespan of the fuel elements, as well as the overall safety of the nuclear reactor. Therefore, measuring the thickness of this layer is crucial in ensuring the optimal operation of the reactor.

2. How is the thickness of oxidation layer on fuel elements measured?

The thickness of oxidation layer on fuel elements is typically measured using a technique called profilometry. This involves using a specialized instrument, such as a scanning electron microscope or atomic force microscope, to scan the surface of the fuel element and measure the depth of the oxide layer. Other techniques, such as X-ray photoelectron spectroscopy, can also be used to determine the thickness of the oxidation layer.

3. What factors can affect the thickness of oxidation layer on fuel elements?

The thickness of oxidation layer on fuel elements can be influenced by a variety of factors, including the temperature and pressure conditions in the reactor, the composition and properties of the fuel material, and the type and concentration of oxidizing agents present. It can also be affected by the design and geometry of the fuel element itself, as well as the presence of any protective coatings or cladding.

4. How does the thickness of oxidation layer on fuel elements impact reactor performance?

The thickness of oxidation layer on fuel elements is directly related to the amount of fuel material that is consumed during the nuclear reaction. A thicker oxidation layer means that more of the fuel material has been oxidized, resulting in a decrease in the amount of fuel available for fission reactions. This can lead to a decrease in reactor power output and efficiency, and may also increase the risk of fuel element failure.

5. Can the thickness of oxidation layer on fuel elements be controlled?

Yes, the thickness of oxidation layer on fuel elements can be controlled through various means. This can include adjusting the temperature and pressure conditions in the reactor, modifying the composition of the fuel material, or adding protective coatings or cladding to the fuel element. Regular monitoring and measurement of the oxidation layer thickness can also help to identify any potential issues and allow for adjustments to be made.

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