Finding Expectation Value of Electric Dipole Moment Matrix Form

In summary, the conversation discusses finding the expectation value of electric dipole moment in matrix form, given the eigenstates of the system and its current state. The solution involves taking the integral of the operator in the given state and simplifying it to |c_1|^2 + |c_2|^2, with the last two terms being zero due to the orthogonal eigenstates. However, it is unclear how to represent the operator mu in matrix form, since it is typically defined as a product of the electron charge and position operator.
  • #1
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Homework Statement


I we know the eigenstates of the system be [tex]|\psi_1\rangle[/tex] and [tex]|\psi_2\rangle[/tex]. Current state of the system is

[tex]|\Psi\rangle = c_1 |\psi_1\rangle + c_2 |\psi_2\rangle[/tex]

Try to find the expectation value of electric dipole moment [tex]\mu[/tex] (assume it is real) and write it in matrix form

2. The attempt at a solution
The expectation value of something is just the integral of that operator in given state, so

[tex]\langle \mu \rangle = \int \Psi^* \mu \Psi d^3x = \int (c_1^* \psi_1^* + c_2^* \psi_2^*)\mu(c_1 \psi_1 + c_2 \psi_2) = |c_1|^2 + |c_2|^2 + \int c_1^*c_2\psi_1^*\psi_2d^3x + \int c_1c_2^*\psi_1\psi_2^*d^3x[/tex]


The last two terms are zero because the eigenstates are orthogonal to each other, right?

so

[tex]\langle \mu \rangle = \mu|c_1|^2 + \mu|c_2|^2 [/tex]


Is this correct? But what does it mean by writing it as matrix form?
 
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  • #2
Isn't mu an operator defined by mu = ex, where e is the electron charge and x is the position operator. I think you treated mu as a number.
 

1. How is the expectation value of electric dipole moment calculated?

The expectation value of electric dipole moment is calculated by taking the product of the electric dipole moment operator and the wavefunction, and then integrating over all space.

2. What is the significance of the electric dipole moment matrix form?

The electric dipole moment matrix form allows for a more comprehensive understanding of the electric dipole moment, as it takes into account the orientation and magnitude of the dipole moment in all three dimensions.

3. What does the electric dipole moment represent?

The electric dipole moment represents the separation of positive and negative charges within a system, and is a measure of the system's polarity.

4. How can the expectation value of electric dipole moment be experimentally measured?

The expectation value of electric dipole moment can be measured experimentally using techniques such as microwave spectroscopy or electric field gradient measurements.

5. What factors can affect the value of the electric dipole moment?

The value of the electric dipole moment can be affected by various factors such as the magnitude and direction of the charges, the distance between them, and the medium in which the charges are located.

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