Ionization Processes in an Electric Field: Single vs. Multiple Ionization

In summary, the conversation discusses the process of ionization and multiple ionization in an electric field. The ionization threshold for the first electron is usually the lowest, and after an atom is ionized, it may accelerate and undergo collisional ionization. Additionally, there is the possibility of electron ionization by a free accelerated electron induced by an electric field. A relevant study on laser induced tunneling ionization is also mentioned.
  • #1
HMS-776
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I have been wondering how an atom is ionized and multiply ionized in an electric field?

In a single ionization, does only one electron go through each transition until it is ionized?

What about in a multiple ionization?

Would the first electron travel through all transitions while the other electrons remain at their ground state? And after the first ionization will the next electron travel through it's transitions until it becomes ionized etc etc?

Or will all the valence electrons travel through their transitions and become ionized at the same time?
 
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  • #2
dear HMS-
Look at my posts in your other threads. Look especially at the ionization thresholds (steps) in beryllium 1s and 2s cross sections in
http://xdb.lbl.gov/Section1/Sec_1-5.html
Usually the ionization threshold for the first electron is the lowest. Once an atom is ionized, the ion will accelerate in an electric field, and collisional ionization becomes possible. In electric field ionization, another possible complication is electron ionization of atoms by a free accelerated electron resulting from an electric field induced ionization of another atom. This is the source of multiplication in Geiger-Muller tubes and proportional counters.
[Edit] See this abstract on laser induced tunneling ionization:
http://www.sciencemag.org/cgi/content/abstract/325/5946/1364
Bob S
 
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  • #3
Thanks for the Links and info BOB S! It is appreciated!
 

1. What is ionization order?

Ionization order refers to the sequence in which electrons are removed from an atom when it is ionized. This order is determined by the energy levels of the electrons and follows a specific pattern.

2. How is the ionization order of an atom determined?

The ionization order of an atom is determined by the energy levels of the electrons. Electrons in an atom are arranged in specific energy levels or shells, and the outermost shell is known as the valence shell. When an atom is ionized, electrons are removed from the outermost shell first, followed by the next shell, and so on, in increasing order of energy levels.

3. Why is the ionization order important?

The ionization order is important because it helps us understand the chemical and physical properties of an element. The number of electrons in the outermost shell, which is determined by the ionization order, affects an atom's reactivity and ability to form chemical bonds.

4. How does the ionization order of an atom affect its ionization energy?

The ionization energy of an atom is the amount of energy required to remove an electron from it. The ionization order of an atom directly affects its ionization energy, as electrons in higher energy levels are more tightly bound to the nucleus and require more energy to be removed compared to those in lower energy levels.

5. Can the ionization order of an atom be changed?

No, the ionization order of an atom is a fundamental property and cannot be changed. It is determined by the number and arrangement of electrons in an atom, which is a characteristic of each element. However, the ionization energy of an atom can be altered by external factors such as temperature and pressure.

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