Catalytic decomposition of nitrous oxide?

In summary, the conversation discusses using materials such as platinum, palladium, and rhodium as catalysts to decrease the activation energy of the decomposition of 2N_2O->2N_2 +O_2. Other materials such as cerium, iron, and nickel are also mentioned, but each has its own limitations. The melting temperatures of these materials are also discussed, with rhodium having the highest melting point. The conversation also mentions the use of cobalt and copper in Fischer-Tropsch synthesis, which involves combining H2 and CO to form alkanes or alkenes.
  • #1
rocketman
5
1
Does anyone know what types of materials may be used to decrease the activation energy of 2N_2O->2N_2 +O_2. I think perhaps silver may work, but I need to find a material which will withstand the high temperature of decomposition

thanks
 
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  • #2
Platinum, palladium and rhodium are two metals that serve as catalysts converting NOx to nitrogen and oxygen.

http://en.wikipedia.org/wiki/Catalytic_converter#Purpose_and_function_of_catalytic_converters

http://en.wikipedia.org/wiki/Catalytic_converter

The catalyst itself, most often a precious metal. Platinum is the most active catalyst, and is widely used. However, it is not suitable for all applications because of unwanted additional reactions and/or cost. Palladium and rhodium are two other precious metals that are used, Palladium as a substitute for Platinum in three-way catalytic converters, and Rhodium is the material that makes a three-way reaction possible. Cerium, iron, and nickel are also used, though each has its own limitations. Nickel is not legal for use in the European Union (nickel hydrate formation). While copper can be used, its use is illegal in North America due to the formation of dioxin.
Wikipedia

Other references:

http://www.schoolscience.co.uk/content/5/chemistry/catalysis/catsch3pg11.html

http://www.chemistry.org/portal/a/c/s/1/feature_ent.html?id=9a4f4f92320b11d7f4a56ed9fe800100
 
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  • #3
Do you know the melting point of any of these catalysts? The decomposition of NOX can serve as a gas generator, creating oxygen and nitrogen, and can thermally sustain itself in the presence of a catalyst with relatively little activation energy. I would like to find a way to cost effectively decompose NOX into its constituants in an adiabatic reaction for the purposes of 1) heating and expanding the flow, and 2) creating free oxygen. I knew of the precious metal approach, but it seems a bit fiscally difficult. Also, I may be mistaken but I believe N2O is not a major byproduct of car emmissions such as NO or NO2 and various other oxygen rich nitrogen oxides.
 
  • #4
Melting temperatures for the elements can be found at www.webelements.com

Rh is in the same group as Co.

Co, 1768 K [or 1495 °C (2723 °F)]
Rh, 2237K [or 1964 °C (3567 °F)]

Pd and Pt are in the Ni group.

Ni, 1728 K [or 1455 °C (2651 °F)]
Pd, 1828.05 K [or 1554.9 °C (2830.82 °F)]
Pt, 2041.4 K [or 1768.3 °C (3214.9 °F)]

Cu, 1357.77 K [or 1084.62 °C (1984.32 °F)]

Co and Cu are used in Fischer-Tropsch synthesis in which H2 and CO are combined to form alkanes or alkenes.

BTW, NOx generally refers to NO and NO2.
 
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1. What is catalytic decomposition of nitrous oxide?

Catalytic decomposition of nitrous oxide is a process in which nitrous oxide (N2O) is broken down into its constituent gases, nitrogen (N2) and oxygen (O2), using a catalyst. This reaction is also known as the "nitrous oxide reduction" reaction.

2. Why is catalytic decomposition of nitrous oxide important?

Catalytic decomposition of nitrous oxide is important because nitrous oxide is a potent greenhouse gas and a major contributor to climate change. By breaking it down into its harmless components, the process helps to reduce the amount of nitrous oxide in the atmosphere and mitigate its negative impact on the environment.

3. How does catalytic decomposition of nitrous oxide work?

In the process of catalytic decomposition of nitrous oxide, the nitrous oxide molecules come into contact with a catalyst, such as platinum or palladium, which lowers the activation energy required for the reaction to occur. This allows the molecules to break apart into nitrogen and oxygen at a much faster rate than they would under normal conditions.

4. What are the applications of catalytic decomposition of nitrous oxide?

Catalytic decomposition of nitrous oxide has a wide range of applications, including reducing greenhouse gas emissions from industrial processes, such as the production of nylon and nitric acid. It is also used in the medical field to remove excess nitrous oxide from anesthesia gas mixtures and in rocket propulsion systems to produce a high-temperature, non-toxic gas for propelling rockets.

5. Are there any drawbacks to catalytic decomposition of nitrous oxide?

One potential drawback of catalytic decomposition of nitrous oxide is the high cost of the catalysts used in the process. Additionally, the process may produce harmful byproducts, such as nitrogen oxides, if not carefully controlled. However, advancements in technology and research are constantly being made to address these issues and make catalytic decomposition of nitrous oxide more efficient and environmentally friendly.

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