Chemistry, Equilibrium Constant Question

In summary, the conversation is about finding the number of moles of NaOH needed to create a buffer with a pH of 7.80 using 500.0 mL of 0.70 M HClO. The Henderson-Hasselbalch equation is used to determine the ratio of weak base to weak acid needed for the buffer, which is found to be 2.19. This ratio is then used to calculate the number of moles of base needed, which is 0.240 moles. The initial amount of HClO and the amount of base added will result in a final solution with 0.35-x moles of acid and x moles of base.
  • #1
jaguar7
42
0
Haha --- nvm, found it. Sorry/Thanks... ^_^

Where does the 2.19 come from?

How many moles of NaOH would need to be added to 500.0 mL of 0.70 M HClO to create a buffer with a pH of 7.80?

Initially, we have 0.35 mol of HClO. We are going to add NaOH which will react with the weak acid to create the conjugate weak base.

HClO + OH- → H2O + ClO-It is this weak base we’ll need to have for the buffer. First, let’s find the ratio of the weak base to the weak acid using the Henderson-Hasselbalch equation:

7.80 = -log(3.5*10^(-8) + log(base/acid)

base/acid = 2.19

Since we will be making base from the weak acid, we will react x moles of OH-. So after the reaction takes place, we have 0.35 – x moles of acid and x moles of base.

x / (0.35 - x) = 2.19

x = 0.240 moles
 
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  • #2
Won't hurt if you will explain what you were asking for and what you have found. I guess I can guess, not so sure about others.
 

1. What is the equilibrium constant?

The equilibrium constant, denoted as Kc or Kp, is a value that represents the ratio of product concentrations to reactant concentrations at equilibrium in a chemical reaction. It is a measure of the extent to which a reaction proceeds to form products.

2. How is the equilibrium constant calculated?

The equilibrium constant is calculated by taking the concentration of products raised to their respective stoichiometric coefficients, divided by the concentration of reactants raised to their respective stoichiometric coefficients. This is represented by the equation Kc = [products]coefficients / [reactants]coefficients.

3. What does the value of the equilibrium constant indicate?

The value of the equilibrium constant indicates whether a reaction favors the formation of products or reactants at equilibrium. A value greater than 1 indicates a higher concentration of products at equilibrium, while a value less than 1 indicates a higher concentration of reactants at equilibrium.

4. How does temperature affect the equilibrium constant?

Temperature has a significant effect on the equilibrium constant. In exothermic reactions, an increase in temperature will lead to a decrease in the value of Kc, as the reaction will favor the formation of reactants to absorb the excess heat. In endothermic reactions, an increase in temperature will lead to an increase in the value of Kc, as the reaction will favor the formation of products to absorb the excess heat.

5. Can the equilibrium constant be altered?

The equilibrium constant is a characteristic of a specific reaction at a specific temperature, and it cannot be altered. However, the equilibrium position can be changed by altering the concentration of reactants and products, or by changing the temperature of the system. This will affect the value of the equilibrium constant.

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