Finite Well Potential - Unbound eigenfunction

In summary, the form of a typical unbound standing wave eigenfunction for a finite square well potential is characterized by a solution of Asin(k_0x) inside the well, where k_0 is greater than the solution outside the well, which is of form Bsin(k_1x + \phi). This means that the eigenfunction's frequency is higher inside the well. It is also suggested that the amplitude of the eigenfunction decreases inside the well, which is explained by the particle having more energy and moving faster, spending less time inside the well. However, it is best to compare the amplitudes of the relevant waves mathematically.
  • #1
quanticism
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Homework Statement



From qualitative arguments, make a sketch of the form of a typical unbound standing wave eigenfunction for a finite square well potential.

An unbound particle is one which has total energy E greater than the Potential V of the well

Is the amplitude of the oscillation the same in all regions?

Homework Equations



Using the Time Independent Schrodinger Equation we see that:

The Attempt at a Solution



Inside well: Solution is of form [tex]Asin(k_0x)[/tex] where [tex]k_0 = \sqrt{2mE/\hbar^2}[/tex]

Outside well: Solution is of from [tex]Bsin(k_1x + \phi)[/tex] where [tex]k_1 = \sqrt{2m(E-V)/\hbar^2}[/tex] where [tex]\phi[/tex] is the phase shift which can be adjusted to satisfy the boundary conditions.

So inside the well, the wave number of the eigenfunction should be greater than the eigenfunction outside the well. This should mean that the eigenfunction's frequency inside the well is higher.

I've looked around and I found this http://vnatsci.ltu.edu/s_schneider/physlets/main/finite_sqr_well.shtml" . You can look at the unbound states by clicking and dragging your mouse on the black bar on the right with the green lines.

It suggests that the amplitude of the eigenfunction should decrease when inside the quantum well.

I thought the amplitude of the eigenfunction should give you an indication of the probability of finding the particle in that particular region. If so, shouldn't the amplitude be slightly higher inside the well?
 
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  • #2
The intuitive explanation is that inside the well, the particle has more energy relative to the floor of the well. It therefore moves faster, which means it spends less time inside the well than outside.

However, this intuition sometimes fails miserably (i.e. for the lower-energy states of the harmonic oscillator). It's always best to do the math and compare the amplitudes of the relevant waves.
 

1. What is a finite well potential?

A finite well potential is a type of potential energy function used to describe the behavior of a particle in a confined space. It is characterized by having a finite depth and a finite width.

2. What is an unbound eigenfunction?

An unbound eigenfunction is a function that satisfies the Schrödinger equation in the absence of a potential energy. It describes the behavior of a particle that is not confined to a specific region and can have any energy value.

3. How are unbound eigenfunctions related to the finite well potential?

In the finite well potential, the unbound eigenfunctions are used to describe the behavior of the particle in regions outside of the well. These eigenfunctions have a different form from the bound eigenfunctions that describe the behavior of the particle within the well.

4. What information can be obtained from the unbound eigenfunctions in the finite well potential?

The unbound eigenfunctions provide information about the probability of finding the particle at different positions and the energy levels that the particle can have. They can also be used to calculate the transmission and reflection coefficients of the particle.

5. How can the unbound eigenfunctions be used to study real-world systems?

The finite well potential and its unbound eigenfunctions are used in quantum mechanics to model various physical systems, such as atoms, molecules, and semiconductors. By studying these systems, scientists can gain a better understanding of their behavior and make predictions about their properties and interactions.

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