Radial distribution probability

In summary, when finding the probability of finding an electron within a sphere of a certain radius, you can integrate the radial distribution probability function with respect to r from 0 to infinity. The product of the radial distribution function times dr can also give the probability, but if there are additional variables in the wavefunction, it may require additional integrations.
  • #1
hellomister
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Homework Statement


When I'm trying to find the probability of finding an electron within a sphere of a certain radius, do i integrate the radial distribution probability function with respect to r from 0 to infinity? My book says the product of the radial distribution function times dr would give the probability, but I always thought you had to integrate it.


Homework Equations


n/a just looking for a simple answer to my question... i didnt show the homework problem cos i want to do it myself i just want this question answered.

The Attempt at a Solution


I've attempted the problem, i just integrated and I want to know if you should integrate.
 
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  • #2
The probability of finding the particle in a shell of thickness dr having radius r is

[tex]dP=|\psi|^2\:4\pi r^2dr[/tex]

The probability of finding the particle anywhere within a sphere of radius R is

[tex]P=\int^R_0 |\psi|^2\:4\pi r^2dr[/tex]

Does this help?
 
  • #3
yes! helps a ton! Thank you.
 
  • #4
Notice that [tex]4\pi r^{2}[/tex] is the area of the surface of a sphere. This factor looks like that because you only have radial distribution, independent of azimuthal direction,
while if your wavefunction looks like [tex]\psi(r,\theta,\phi)[/tex] things will get a little more complicated, and will involve additional integrations.
 
  • #5


I can confirm that integrating the radial distribution probability function is the correct approach to finding the probability of finding an electron within a sphere of a certain radius. The product of the radial distribution function and dr is simply the differential element used in the integration process. This is a common approach in many areas of science, where we use integration to calculate probabilities or other quantities of interest. Therefore, if you have integrated the function and obtained a solution, you have correctly approached the problem. Keep up the good work!
 

What is radial distribution probability?

Radial distribution probability is a concept in quantum mechanics that describes the probability of finding an electron at a specific distance from the nucleus in an atom.

How is radial distribution probability calculated?

Radial distribution probability is calculated using the radial wave function, which is derived from the Schrödinger equation. This equation takes into account the electron's energy, angular momentum, and the potential of the nucleus.

What does the radial distribution probability tell us about an atom?

The radial distribution probability tells us about the electron density in an atom. It shows the most probable locations for finding electrons, and the probability decreases as the distance from the nucleus increases.

What factors affect the radial distribution probability?

The radial distribution probability is affected by the energy level of the electron, the shape of the atomic orbital, and the number of electrons in the atom. It also depends on the type of atom and its electron configuration.

Why is radial distribution probability important in understanding atomic structure?

Radial distribution probability gives us insight into the distribution of electrons in an atom, which is crucial for understanding its chemical and physical properties. It also helps in predicting the behavior of atoms in chemical reactions and their interactions with other atoms.

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