How does water vapor affect the expansion of butane in a lighter?

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In summary: To find the mole fraction of water vapor in the cylinder, you would need to use the equilibrium constant for water vapor and butane. The equilibrium constant for water vapor and butane is kH2O = 9.14J/Kg mol.
  • #1
kateman
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i was interested if anyone could explain how a butane lighter can expand from liquid state into the gas state with what appears to be, more volume?

it'd be great if you could mention any laws or theories

thanks :)
 
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  • #2
PV=NkT

Liquid is denser than gas.
 
  • #3
thanks

any way/formula of measuring the mass when it changes?

would the combined gas law work in this instance?
 
  • #4
You can measure the mass change with a scale, but the density of the liquid you can probably just google.
 
  • #5
kateman said:
i was interested if anyone could explain how a butane lighter can expand from liquid state into the gas state with what appears to be, more volume?

it'd be great if you could mention any laws or theories

thanks :)
It's a matter of reduced pressure. Inside the lighter casing/reservoir, the pressure is slightly higher than atmospheric pressure. The liquid/vapor inside is satured, such that the pressure is fixed according to temperature. When a little vapor is released (because of the pressure differential between inside and out), more liquid becomes vapor to maintain an equilibrium.

Outside the lighter, the pressure is 1 atm.

See -
http://www.engineeringtoolbox.com/propane-butane-mix-d_1043.html (annoying popups on this site).
Propane is more suited to colder environments since it evaporates at -44°F (-42°C) at atmospheric pressure. Butane evaporates at 33°F (-0.5°C) at atmospheric pressure.

The vapor pressure of a mixture of the two products can be found in the table below:
 
  • #6
thank-you Astronuc, that is exactly what i was after
one more quick question, i did an experiment of using a butane lighter underwater and collecting the gas in an inverted cylinder so that the butane gas displaces the water and from there finding the molar mass of butane.

Well the lighter lost 0.04 grams of butane yet there were 101ml of gas in the cylinder. I worked it out (assuming butane is an ideal gas, which its not) so that butane had a molar mass of 9.46g (which is way off).
The working is right, so what could my experimental error could have been?
 
  • #7
How was the volume of the gas measured? Also, make sure volume measurements are corrected to STP.

Reweigh the lighter.

Also, was the volume dry or was water vapor present. A significant mole fraction of water vapor would drop the molecular mass.

The molar mass is ~58 g/mole.

The density of the gas is 2.52 g/l or 0.00252 g/ml, so with 101 ml, one should have 0.255 g, so one is off somewhere by a factor of about 6.
 
  • #8
the volume of gas was measured by finding the amount of water left in the inverted cylinder and taking it off the total capacity of the cylinder.

water vapor was present. it was taken of the room pressure to give the butane pressure.


"A significant mole fraction of water vapor would drop the molecular mass."
how would find the volume of water vapor in the cylinder and express that mole fraction algebraically?
 

1. What is butane lighter expansion?

Butane lighter expansion is a phenomenon that occurs when the temperature of a butane lighter increases, causing the butane inside the lighter to expand and create a higher pressure. This increased pressure allows for the butane to be released as a gas through the lighter's nozzle, creating a flame.

2. Why does butane lighter expansion happen?

Butane lighter expansion happens because of the ideal gas law, which states that as the temperature of a gas increases, its volume and pressure also increase. This is due to the increased kinetic energy of the gas molecules, causing them to move faster and take up more space.

3. Is butane lighter expansion dangerous?

In most cases, butane lighter expansion is not dangerous. However, if a lighter is exposed to extreme heat or left in a hot environment for a prolonged period of time, the pressure inside the lighter can become too high and potentially cause the lighter to explode. It is important to use caution and store lighters in a cool, dry place.

4. How does butane lighter expansion affect the flame?

Butane lighter expansion has a direct effect on the size and intensity of the flame. As the pressure inside the lighter increases, more butane is released through the nozzle, creating a larger and hotter flame. This is why a lighter may have a bigger flame when first lit compared to after it has been used for a while and cooled down.

5. Can butane lighter expansion be controlled?

Yes, butane lighter expansion can be controlled by adjusting the temperature of the lighter. If a lighter is too hot and the pressure is too high, allowing it to cool down before use can help prevent a potentially dangerous situation. Additionally, some lighters have adjustable flame settings that can control the amount of butane released and the size of the flame.

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