Finding the dipole moment of a molecule in an electric field

In summary: So the change in potential energy is:ΔU = -pEcos(π) - (-pEcos(0)) = -(-pE) - (-pEcos(0)) = pE - (-pE) = 2pESince we know the change in potential energy, we can set that equal to the energy required to reverse the dipole's orientation and solve for p:2pE = 3.5x10^(-27) J p = 3.5x10^(-27) J / (2*1.8 kN/C) = 9.72x10^-31 C-m Therefore, the dipole moment is 9.72x
  • #1
Les talons
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Homework Statement


"A molecule has its dipole moment aligned with a 1.8 kN/C electric field. If it takes 3.5x10^(-27) J to reverse the molecule's orientation, what is its dipole moment?"


Homework Equations


Potential energy of dipole in an electric field
U = -p*E = -p*E*cos(theta)

U = 0 corresponds to the dipole aligned at right angles to the field

Torque on a dipole in an electric field
tau = p X E

Dipole moment vector is the product of the equal and opposite charges separated by distance d
p = qd



The Attempt at a Solution


Greetings. My solution attempt is as follows:
U = -p*E
energy required to reverse dipole's orientation = potential energy of the dipole
From this I found:
-3.5x10^(-27) J /1.8 kN/C = -1.9x10^-30 C-m
But this is wrong and I don't know why. The dimensional analysis shows the correct units using this approach.
Then I tried to included the cos(theta) for the magnitude of the dot product, taking theta as pi because the dipole has to have its orientation reversed, and this produced the answer 1.9x10^-30 C-m, which is also incorrect.

I assume that the dipole has no kinetic energy since it is not described as moving, so the energy needed to reverse it's orientation must be large enough to equal its potential energy. This energy has to be applied by doing work on the dipole, which is given, but since there are no charges or distance given, I cannot use p = qd. Then because I don't have p, the torque equation does not help. I must be overlooking something really simple. There are no examples like this in my book. The ones I have found on other sites all show the approach that I tried, so they are no help. The professor did not discuss dipole moments in lecture and none of his slides have a calculation of it, but do show finding the electric field generated by a dipole, which does not work since the problem does not give a charge, q.

If anybody has any comments or ideas, they would be greatly appreciated. Cheers.
 
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  • #2
Hello, Les talons. Welcome to PF!

Les talons said:
My solution attempt is as follows:
U = -p*E
energy required to reverse dipole's orientation = potential energy of the dipole

That's not quite right. The energy required is equal to the change in potential energy of the dipole.

What are the initial and final values of θ?
 
  • #3
Thank you for answering. There are no values given so does that mean we can assign our own coordinate system? Initially, the dipole is aligned, so theta = 0, and at the final position the dipole moves orientation, so theta = pi. I do know at theta = pi/2 the dipole will have U = 0. Would this be the right formula for the change in U: p*E*cos(theta_final) -p*E*cos(theta_initial)?
 
Last edited:
  • #4
Les talons said:
Initially, the dipole is aligned, so theta = 0, and at the final position the dipole moves orientation, so theta = pi. I do know at theta = pi/2 the dipole will have U = 0.

Right.

Would this be the right formula for the change in U: p*E*cos(theta_final) -p*E*cos(theta_initial)?

Yes, except don't forget that there is a negative sign in the expression for U:
U = -pEcosθ
 
  • #5




Thank you for sharing your attempted solution and thought process. It seems like you have a good understanding of the relevant equations and concepts. However, there are a few key pieces of information missing from the problem that are needed to find the dipole moment.

Firstly, the problem does not specify the distance between the equal and opposite charges that make up the dipole moment. Without this distance, we cannot use the equation p = qd to find the dipole moment.

Secondly, the problem does not mention anything about the strength of the charges that make up the dipole. Without this information, we cannot use the torque equation tau = p X E to find the dipole moment.

It is possible that there is a missing piece of information or a typo in the problem. If you have access to the textbook or lecture notes, I would recommend checking for any additional information or clarifications. Otherwise, you may need to bring this issue to the attention of your professor or teaching assistant.

In general, when solving physics problems, it is important to carefully consider all the given information and what information is needed to solve the problem. If any information is missing, it is important to clearly state that in your solution and explain how it affects your ability to find the solution.

I hope this helps and good luck with your studies.
 

1. How is the dipole moment of a molecule defined?

The dipole moment of a molecule is defined as the measure of the separation of positive and negative charges within the molecule, and the magnitude of this separation.

2. What is an electric field and how does it affect the dipole moment of a molecule?

An electric field is a region in space where charged particles experience a force. When a molecule is placed in an electric field, the field exerts a force on the molecule's charged particles, causing a shift in the molecule's dipole moment.

3. How can the dipole moment of a molecule be experimentally determined?

The dipole moment of a molecule can be experimentally determined by measuring the electric field strength required to align the molecule's dipole moment with the field. This can be done using techniques such as spectroscopy or dielectric constant measurements.

4. What factors affect the dipole moment of a molecule?

The dipole moment of a molecule is affected by the magnitude and direction of the charges within the molecule, as well as the distance between them. The molecular structure, symmetry, and bond polarities also play a role in determining the dipole moment.

5. Why is the dipole moment of a molecule important?

The dipole moment of a molecule is important because it provides information about the molecule's polarity and its interactions with other molecules. It is also a key factor in determining the molecule's physical and chemical properties, such as solubility, boiling point, and reactivity.

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