Naming Cyclohexene with E/Z Configuration

In summary, when naming cyclohexene with E/Z configuration, consider the higher priority atoms attached to each carbon of the double bond separately. If they are on the same side, it is Z configuration and if they are on opposite sides, it is E configuration. However, in practice, it is unlikely to have an (E) cyclohexene with only carbon and hydrogen due to sterics. An easy way to remember is Z for "Zame" side and E for different sides.
  • #1
zorro
1,384
0
How do we name cyclohexene with E/Z configuration?

This compound is symmetric w.r.t. the double bond.
 
Chemistry news on Phys.org
  • #2
Abdul Quadeer said:
How do we name cyclohexene with E/Z configuration?

This compound is symmetric w.r.t. the double bond.

Consider the two atoms attached to each carbon of the double bond separately. Are the higher priority atoms on the same, or opposite sides of the double bond?
 
  • #3
We have a C--C double bond and one CH2- group + H- atom on each carbon.
The two CH2- groups are on one side. So is it Z?
 
  • #4
Yes, though in practice you are unlikely to get an (E) cyclohexene if all you have is carbon and hydrogen due to sterics.
 
  • #5
An easy way to remember this (I use this method):

Z - "Zame" side

E - different sides
 
  • #6
Yes, though in practice you are unlikely to get an (E) cyclohexene if all you have is carbon and hydrogen due to sterics.

Thanks!

Z - "Zame" side

Lol.
Thanks for that. I always had trouble rememebering them.
 

1. What is the E/Z configuration in cyclohexene?

The E/Z configuration is a way to describe the arrangement of substituents on a double bond in a molecule. In cyclohexene, the E configuration means that the two highest priority substituents are on opposite sides of the double bond, while the Z configuration means they are on the same side.

2. How do you determine the E/Z configuration in cyclohexene?

To determine the E/Z configuration in cyclohexene, you need to identify the two highest priority substituents on the double bond. This is done by assigning each substituent a priority based on the atomic number of the atoms directly bonded to the double bond. Then, if the two highest priority substituents are on the opposite sides of the double bond, it is E configuration. If they are on the same side, it is Z configuration.

3. What is the difference between E and Z configuration?

The main difference between E and Z configuration is the arrangement of the substituents on the double bond. In E configuration, the two highest priority substituents are on opposite sides of the double bond, while in Z configuration, they are on the same side. This can affect the physical and chemical properties of the molecule.

4. How do you name cyclohexene with E/Z configuration?

To name cyclohexene with E/Z configuration, first identify the two highest priority substituents on the double bond. Then, use the prefix "E" or "Z" before the name of the molecule, followed by a hyphen and the name of the molecule. For example, if the molecule has an E configuration, it would be named as "E-cyclohexene".

5. Can a molecule have both E and Z configuration?

Yes, a molecule can have both E and Z configuration. This is known as a cis-trans isomerism, where two or more compounds have the same molecular formula but different spatial arrangements. In this case, the molecule will have a double bond that can rotate, allowing for the E and Z configurations to interchange.

Similar threads

  • Chemistry
Replies
1
Views
993
Replies
3
Views
1K
Replies
4
Views
3K
  • Chemistry
Replies
2
Views
10K
Replies
1
Views
975
  • Quantum Physics
Replies
1
Views
613
  • Chemistry
Replies
1
Views
2K
  • Biology and Chemistry Homework Help
Replies
8
Views
725
Replies
2
Views
5K
Back
Top