RMS displacement of a diatomic atom

In summary, the provided information discusses a hypothetical diatomic atom with an equilibrium distance and an effective spring constant. The amplitude of the atom's vibration increases with temperature, and the question asks for the temperature at which the rms displacement will be a given value. To solve this, one must consider the atom as a classical harmonic oscillator and use equations relating energy and amplitude to determine the answer.
  • #1
Erubus
22
0

Homework Statement


A hypothetical atom is diatomic containing two identical atoms separated by an equilibrium distance. About this distance the atoms vibrate with the electric forces providing an effective spring constant of k = 4.0×10^−3 N/m. As the temperature of the sample is increased the amplitude of the vibration increases. At what temperature will the rms displacement of the atoms be x= 5.0×10−10m? (Answer: 72 K)


Homework Equations


<E> = 7kT/2

U = 7nRT/2


The Attempt at a Solution



I assumed that because of spring like nature of the atoms, this atom was a diatomic non rigid rotator, which is how I have those relevant equations. I am unsure if this initial assumption is even correct. Even if it was, I still don't have an idea of how to proceed from there.
 
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  • #2
It seems that you need to be modelling the bond as a harmonic oscillator. I imagine also that this should be considered as a classical oscillator, and not quantum mechanical. Then, you need to take out your classical mechanics textbook and figure out the relation between the energy of the oscillator and the amplitude of the oscillation, which will be related to the rms displacement ##\sqrt{\langle x^2 \rangle}##.
 
  • #3
Got it, thanks.
 

1. What is RMS displacement?

RMS displacement, also known as root-mean-square displacement, is a measure of the average distance a diatomic atom travels from its equilibrium position over a period of time. It is a useful tool for understanding the motion and behavior of atoms in a system.

2. How is RMS displacement calculated?

RMS displacement is calculated by taking the square root of the average of the squared displacements of the atom from its equilibrium position. This is often done using computer simulations or mathematical models.

3. What factors affect the RMS displacement of a diatomic atom?

The RMS displacement of a diatomic atom is affected by factors such as temperature, pressure, and the strength of interatomic bonds. Higher temperatures and pressures generally result in larger RMS displacements, while stronger bonds may lead to smaller RMS displacements.

4. How does RMS displacement relate to the kinetic energy of a diatomic atom?

The RMS displacement of a diatomic atom is directly related to its kinetic energy. As the RMS displacement increases, so does the kinetic energy of the atom. This is because a larger RMS displacement means the atom is traveling further from its equilibrium position, and thus has a greater velocity and kinetic energy.

5. Why is RMS displacement important in studying diatomic atoms?

RMS displacement is important in studying diatomic atoms because it provides insight into their behavior and properties. It can help us understand how these atoms move and interact with each other, and how they respond to changes in their environment. This information is crucial in fields such as materials science and chemistry.

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