Transition metal oxidation states

In summary, Ni only forms NiO with an oxidation state of +2, unlike other transition metals which can form a wide range of oxides with variable oxidation states. This is due to the d-electrons shielding poorly from the nuclear charge, causing an increase in effective nuclear charge as the number of d-electrons increases. Additionally, the energy of the d-electrons decreases when going from left to right in the period, leading to them not participating in bonding at the end of the period.
  • #1
Moogie
168
1
Hi

Why does Ni only form NiO with oxidation state of +2 whereas the other transition metals form a wide range of oxides with variable oxidation states

Thanks
 
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  • #2
It behaves the same way as do Zn and Copper which are its neighbours.
The reason is that the d-electrons shield each other only badly from the nuclear charge. Hence the effective nuclear charge increases (Google for Slater rules) when the number of d-electrons increases and the energy of the d-electrons relative to the valence s-electrons drops when going in the period from left to right so that they participate no longer in bonding at the end of the period.
 

What are transition metal oxidation states?

Transition metal oxidation states refer to the number of electrons that a transition metal atom has lost, gained, or shared during a chemical reaction. This number determines the overall charge of the atom and its ability to form chemical bonds with other atoms.

How are transition metal oxidation states determined?

Transition metal oxidation states can be determined by analyzing the electronic structure of the atom. This includes the number of valence electrons and the energy levels of the electrons. The number of oxidation states that a transition metal can have is related to its position in the periodic table.

What is the most common oxidation state for transition metals?

The most common oxidation state for transition metals is +2. This is because transition metals have two valence electrons in their outermost energy level, making it easier for them to lose those electrons and form a stable +2 charge.

Can transition metals have multiple oxidation states?

Yes, transition metals can have multiple oxidation states. This is because they have several energy levels and can lose or gain electrons from different levels, resulting in different oxidation states. For example, iron can have an oxidation state of +2 or +3.

Why do transition metals have variable oxidation states?

Transition metals have variable oxidation states because of their unique electronic structure. They have partially filled d-orbitals, which makes it easier for them to gain or lose electrons from different energy levels. This allows them to form multiple oxidation states and participate in a variety of chemical reactions.

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