Understanding Zeeman Effect Selection Rules | Exploring Spin Physics

In summary, selection rules are a set of rules that determine which transitions are allowed between energy levels in an atom or molecule. They are important in spectroscopy because they help predict which transitions are allowed and provide information about the energy levels and structure of atoms and molecules. These rules may differ depending on the type of spectroscopy being used, and are generally considered to be unbreakable, although they may be relaxed or violated in certain situations. Selection rules are determined experimentally through spectroscopic measurements.
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I am reading some online article on Zeeman effect
http://math.ucr.edu/home/baez/spin/node10.html
In the article, the author mentions 4 selection rules, I wonder the corresponding transition is allowed by satisfying one of these selection rules or the corresponding line will be allowed only when all rules are satisfied?

Thanks.
 
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All four selection rules must be satisfied.
 
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I can provide some clarification on the selection rules mentioned in the article on Zeeman effect. The four selection rules mentioned (ΔJ = 0, ΔM_J = 0, ΔM_1 = 0, ΔM_2 = 0) refer to the change in angular momentum and magnetic quantum numbers between the initial and final states of an atom or molecule.

These selection rules determine which transitions are allowed or forbidden in the presence of an external magnetic field. When all four rules are satisfied, the transition is allowed and will result in a spectral line in the Zeeman effect. However, if any of the rules are not satisfied, the transition is forbidden and no spectral line will be observed.

It is important to note that these selection rules are not absolute and there can be exceptions depending on the specific system being studied. Additionally, the strength of the spectral line will also depend on how well the selection rules are satisfied.

Overall, the selection rules in the Zeeman effect provide a framework for understanding the behavior of atoms and molecules in a magnetic field and help us interpret the resulting spectral lines. Further research and experimentation are necessary to fully understand the complexities of the Zeeman effect and its applications in spin physics.
 

1. What are selection rules in science?

Selection rules are a set of rules that determine which transitions are allowed between energy levels in an atom or molecule. These rules are based on conservation laws, such as conservation of energy and angular momentum.

2. Why are selection rules important in spectroscopy?

Selection rules are important in spectroscopy because they help to predict which transitions are allowed and which are forbidden, providing valuable information about the energy levels and structure of atoms and molecules.

3. How do selection rules differ for different types of spectroscopy?

Selection rules may differ for different types of spectroscopy, depending on the type of interaction between the radiation and the atoms or molecules. For example, in electronic spectroscopy, selection rules are based on changes in electronic energy levels, while in vibrational spectroscopy, they are based on changes in molecular vibrational energy levels.

4. Can selection rules be violated?

Selection rules are based on fundamental laws of physics and are generally considered to be unbreakable. However, in certain situations, such as in highly excited states or in the presence of strong external fields, these rules may be relaxed or violated.

5. How are selection rules determined experimentally?

Selection rules are typically determined experimentally through spectroscopic measurements. By analyzing the spectral lines and their intensities, scientists can identify which transitions are allowed and use this information to determine the corresponding selection rules.

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