Using a Platinum Electrode & HCl in a Standard Hydrogen Electrode

In summary, a platinum electrode is used in a standard hydrogen electrode to facilitate electron transfer and provide a stable surface for reactions to occur on. HCl is added to maintain the stability and accuracy of the electrode. While other materials can be used, platinum is preferred for its conductivity and stability. The standard hydrogen electrode measures electrode potential by comparing it to the known potential of the hydrogen electrode. Safety precautions should be taken when handling both the platinum electrode and HCl, including wearing protective equipment and properly cleaning and storing the electrode after use.
  • #1
smart_worker
131
1
In Standard Hydrogen Electrode why only Platinum electrode should be used and why should it be dipped in HCl?why can't we use any other metal dipped in any other acid other than HCl?
 
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  • #2
Not just a platinum electrode, but electrode covered with so called platinum black - that guarantees very fast reaction (so the potential is not changed by the reaction kinetics). Cl- is just a very good, inert counter anion, with reasonably high diffusion coefficient (so the solution has as low resistance as possible).
 

1. What is the purpose of using a platinum electrode in a standard hydrogen electrode?

The platinum electrode is used as a conductive surface to facilitate electron transfer in the electrochemical reaction. It also provides a stable and inert surface for the reaction to occur on.

2. How does HCl affect the standard hydrogen electrode?

HCl, or hydrochloric acid, is added to the standard hydrogen electrode to create a more acidic environment. This helps to maintain the stability and accuracy of the electrode by preventing any potential changes in pH.

3. Can any other electrode be used instead of platinum?

While platinum is the most commonly used electrode in a standard hydrogen electrode, other materials such as gold, silver, or carbon can also be used. However, platinum is preferred due to its high conductivity and chemical stability.

4. How does the standard hydrogen electrode measure electrode potential?

The standard hydrogen electrode measures the potential of other electrodes by comparing them to the known potential of the hydrogen electrode. The electrode potential is measured based on the difference in potential between the two electrodes.

5. Are there any safety precautions that should be taken when using a platinum electrode and HCl?

Yes, it is important to handle HCl with caution as it is a strong acid and can cause burns. Proper protective equipment, such as gloves and goggles, should be worn when handling both the platinum electrode and HCl. Additionally, the electrode should be properly cleaned and stored after use to avoid any potential contamination or damage.

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