Why are metals more dense than non-metals?

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In summary, the density of metals compared to non-metals is influenced by several factors such as the bonding, nuclear mass, and orbital size. Metal crystals have short metal-metal bonds due to the small size of d-orbitals, while non-metals are unable to form dense single-element crystals. The contraction of orbitals due to special relativity also contributes to the similar size of heavy metal atoms, resulting in higher densities compared to non-metals.
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dolimitless
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Im guessing it's something to do with their metallic bonding of sorts?
 
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That is often the case, but not always. Compare the densities of lithium, sodium, or even cesium to the densities of bromine and iodine, for instance.

One thing to look at is the periodic table. If you draw a line that separates the metals from the nonmetals, which side of that line do the metals fall on?
 
  • #3
Look at this - http://www.webelements.com/periodicity/density/ - for elements that are solid or liquid at room temperature.

Bonding plays role, but so does the nuclear (atomic) mass and the adding of d-orbitals rather than p-orbitals. Some of transition metals are denser than non-metals in the same period, with group 9 being the densest in periods 4, 5 and 6. The alkali and alkaline Earth elements, groups 1 and 2, are lighter than the solid non-metals in their respective periods.
 
  • #4
There's a bunch of reasons.

Yes, metal-metal bonds in metal crystals (which is what you mean by 'a metal' in everday speech) are relatively short. This is related to another factor, which is that since metals have d-orbitals as their valence shell, they're smaller - d orbitals are small. (by whatever measure you use to define the radius of an atom, there's no agreed-upon one) By comparison, s-orbitals are quite big, which is why lithium is very light - not only does it have a low atomic number, but it's surrounding electron cloud is quite big, relatively speaking.

Another factor is that non-metals can't form the big single-element crystals that metals can. In the few cases they do (S8 for instance) they're not packed as dense. When they form crystals its usually as an ionic solid, which means the have a counter-ion, and again, they can't be packed as dense.

Yet another factor is the contraction of orbitals due to special relativity. As elements get heavier, the increased positive charge of the nucleus causes the innermost (core) electrons to move faster (classical analogue: a planet orbiting more closely to the sun has to move faster to stay in orbit). They move so much faster that the electrons start to pick up relativistic mass - which causes their orbitals to contract (and the others follow suit). So even though heavy metals have lots and lots more electrons, they're not that much bigger. (E.g. Uranium has 3x the number of electrons Chromium does, but only about 10-25% bigger radius, depending on how you measure it)

So metal atoms are all roughly the same size - so the density of metals compared to other metals is mostly dependent on the atomic weight - and you find the heaviest metals (Tungsten, Osmium & co) right near the bottom of the periodic table. But the density of metals compared with non-metals is mostly due to the other factors.
 

1. Why do metals have higher density than non-metals?

The density of an element is determined by its atomic structure. Metals have a more compact atomic structure compared to non-metals, which allows them to pack more atoms into a given space, resulting in a higher density.

2. What is the relationship between atomic structure and density?

The more compact an element's atomic structure is, the higher its density will be. This is because a compact structure allows for more atoms to be packed into a given space, increasing the overall mass of the element.

3. Are there any exceptions to this trend?

Yes, there are some exceptions to the trend of metals having higher density than non-metals. For example, non-metals such as iodine and sulfur can have a higher density than some metals such as lithium and sodium.

4. How does the size of atoms affect the density of an element?

The size of atoms also plays a role in determining an element's density. Generally, smaller atoms will have a higher density because they can pack more tightly into a given space. This is why metals, which have smaller atoms, tend to have higher density than non-metals with larger atoms.

5. Can density be used to distinguish between metals and non-metals?

Density alone cannot be used to distinguish between metals and non-metals, as there are exceptions to the trend. However, it can be a useful tool when combined with other properties such as conductivity and malleability.

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