What would the products of photolysis degredation of PET plastic be?

In summary, the conversation discusses the potential tainting of plastic drinking bottles when left in the sun due to UV degradation of the PET plastic. The goal is to find a catalyst that can make the PET byproducts non water soluble or able to evaporate. However, this must be balanced with the need for the plastic to not leach into the contents and have a long shelf life. Research has been done on using DBD and UV irradiation treatments on PET and PET+TiO2 films to address this issue. Additional information can be found on the degradation of polymers, pigments, and dyes by UV light.
  • #1
lostminty
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Interested in this because plastic drinking bottles have a taint to them when left out in the sun. I gather its from UV degredation of the PET plastic.

I'd like to find a catalyst that would allow the PET byproducts to be non water soluble/sequester or even evaporate.
 
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  • #2
lostminty said:
Interested in this because plastic drinking bottles have a taint to them when left out in the sun. I gather its from UV degredation of the PET plastic.

I'd like to find a catalyst that would allow the PET byproducts to be non water soluble/sequester or even evaporate.
One has to balance that degradation against the desire for non-leaching of the plastic into the contents and long shelf life.

The exterior surface could be less critical than the interior surface, but it's difficult to treat the interior in a bottle given the geometry.

Here's some research on PET and UV.
Physico-chemical modifications of the DBD and UV irradiation treatments on the PET and PET+TiO2 films
http://134.147.160.41/ispcdocs/ispc16/CostPapers/497.pdf

See also
http://en.wikipedia.org/wiki/Ultraviolet#Degradation_of_polymers.2C_pigments_and_dyes
 
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1. What is photolysis degradation of PET plastic?

Photolysis degradation is a process in which PET (polyethylene terephthalate) plastic is broken down into smaller molecules due to exposure to sunlight or artificial light.

2. What are the products of photolysis degradation of PET plastic?

The products of photolysis degradation of PET plastic can vary depending on the specific conditions of the process. However, some common products include smaller molecules of PET, such as ethylene glycol and terephthalic acid, as well as other byproducts like carbon dioxide.

3. Is photolysis degradation of PET plastic harmful to the environment?

While the products of photolysis degradation are not considered toxic, the process itself can contribute to the pollution of the environment. The fragments of PET plastic can remain in the environment for a long time and can potentially harm wildlife if ingested.

4. How long does photolysis degradation of PET plastic take?

The duration of photolysis degradation can vary depending on factors such as the intensity and duration of sunlight exposure, as well as the type and thickness of the plastic. In general, it can take several months to a few years for significant degradation to occur.

5. Can photolysis degradation of PET plastic be prevented?

While photolysis degradation cannot be completely prevented, it can be slowed down by limiting exposure to sunlight or using additives that can protect the plastic from UV radiation. Proper disposal and recycling of PET plastic can also help prevent the negative effects of photolysis degradation.

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