Heat/First Law of Thermodynamics/Calorimetry - Have work done

In summary, the conversation discusses the concept of heat and the first law of thermodynamics, specifically in relation to calorimetry. The problem at hand involves finding the final temperature of a calorimeter filled with water and ice, using a formula that takes into account the mass and specific heat capacity of each substance. The final temperatures obtained for two different masses of ice are 24.41°C and -6.7167°C. The conversation also touches on the idea that the water and ice will eventually reach the same temperature due to the transfer of heat, as the calorimeter has negligible heat capacity.
  • #1
maniacp08
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0
Heat/First Law of Thermodynamics/Calorimetry -- Have work done

A calorimeter of negligible mass contains 920 g of water at 303 K and 48 g of ice at 273 K. Find the final temperature T.
°C
Solve the same problem if the mass of ice is 460 g.
°C

Formula I've used
Mice * Lf + Mice * Cwater * change in T icewater = Mwater * Cwater * change in T water

(.048kg)(79.7kcal/kg)+(.048kg)(1kcal/kgxK)(Tf - 273K) =
(.92kg)(1kcal/kgxK)(303K-Tf)

Ive gotten Tf to be 297.56K which is 24.41 C

and for part B I've gotten the answer to be 266.433K which is -6.7167 C

Is this correct?
 
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  • #2


I would start with the idea that the -q(water)= q(ice)
This is because the water is warmer and it is losing heat to the ice. It will continue transferring heat until both are at the same temperature. Since the calorimeter has negligible heat capacity, it does not absorb any of the heat that the water gives off.
From here you can say that the -ms(t(fin)-t(int)) for water is equal to ms(t(fin)-t(int)) for the ice.
Hope that helps.
 
  • #3


I cannot confirm if your calculations are correct without seeing your work and the specific values for the specific heat and latent heat of fusion used. However, your approach and use of the first law of thermodynamics and calorimetry principles seem correct. It is always important to double-check your calculations and make sure the units are consistent. Additionally, if possible, it is always beneficial to compare your results with known values or to repeat the experiment to confirm your findings.
 

1. What is heat and how is it related to temperature?

Heat is the transfer of thermal energy from one object to another due to a temperature difference. Temperature is a measure of the average kinetic energy of the particles in a substance. The higher the temperature, the more kinetic energy the particles have, and the more heat they can transfer.

2. What is the First Law of Thermodynamics and what does it state?

The First Law of Thermodynamics states that energy cannot be created or destroyed, only transferred or converted from one form to another. In other words, the total energy in a closed system remains constant.

3. How is the First Law of Thermodynamics applied in everyday life?

The First Law of Thermodynamics can be observed in many everyday activities, such as cooking, driving a car, or using a refrigerator. In these processes, energy is transferred or converted from one form to another, but the total energy remains constant.

4. What is calorimetry and how is it used to measure heat?

Calorimetry is the science of measuring heat transfer. It involves using a calorimeter, a device designed to measure the heat gained or lost by a substance during a physical or chemical process. By measuring the changes in temperature of the substance and the surrounding environment, the amount of heat transferred can be calculated.

5. Can work be done in a system without heat transfer?

Yes, work can be done in a system without heat transfer. In fact, this is the principle behind mechanical engines such as car engines and turbines. These systems convert energy from one form to another, without any heat transfer taking place.

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