Cold and Cryogenic Treating of Steel

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In summary, cold treatment of steel involves exposing the ferrous material to subzero temperatures to improve its properties. Unlike heat treating, which requires precise temperature control, cold treating only requires reaching a minimum low temperature and is not affected by lower temperatures. The process usually consists of a slow cool-down from ambient temperature to liquid nitrogen temperature, followed by a soak period and then warming up to room temperature. The mechanism behind the improved performance of cryogenically treated steel is not well understood, but theories include a more complete transformation of retained austenite into martensite, precipitation of submicroscopic carbides, and a reduction in internal stresses. Some believe that reduced internal stresses may lead to a reduction in microcracking and improved properties. Additional information on
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ASM International said:
Cold treatment of steel consists of exposing the ferrous material to subzero temperatures to either impart or enhance specific conditions or properties of the material.

Unlike heat treating, which requires that temperature be precisely controlled to avoid reversal, successful transformation through cold treating depends only on the attainment of the minimum low temperature (-84°C, or -120°F) and is not affected by lower temperatures. Typical cryogenic treatment consists of a slow cool-down (~2.5°C/min, or 4.5°F/min) from ambient temperature to liquid nitrogen temperature. When the material reaches approximately 80K (-315°F), it is soaked for an appropriate time (generally 24 h). At the end of the soak period, the material is removed from the liquid nitrogen and allowed to warm to room temperature in ambient air. Temperature can be controlled accurately and thermal shock to the material is avoided by conducting the cool-down cycle in gaseous nitrogen.

http://asm.asminternational.org/ht-echarts/3046_OMM120707_figure.pdf
 
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Effects of Cryogenically Treated Steel

ASM International said:
The absence of a clear-cut understanding of the mechanism(s) by which cryogenic treatment improves performance has hindered its widespread acceptance in the industry.

Nevertheless, studies have been conducted to determine the effects of cryogenic treatment. Theories about the reasons for the effects of cryogenic treatment include a more nearly complete transformation of retained austenite into martensite; precipitation of submicroscopic carbides; and a reduction in internal stresses in martensite that occurs when the submicroscopic carbide precipitation occurs.

A reduction in microcracking tendencies resulting from reduced internal stresses is suggested as a reason for improved properties.


http://asm.asminternational.org/ht-echarts/3046_OMM121407_figure.pdf
ASM Handbook, Vol. 4, Heat Treating, ASM International, 1991, p 205


http://www.airproducts.com/NR/rdonlyres/3433A3DC-1899-4093-A094-9964342C38C0/0/33005019GLB.pdf PDF - use 'Save target as'
 
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  • #3
Cool! er... so to speak.

This question keeps coming up over on the Cryogenics forum at Eng-Tips. I'll have to point all such questions over here for further consideration.

Edit - Link to additional information on cryogenic material processing:
http://www.cryogenicsociety.org/publications/cold_facts/current/cryogenic_processing_articles.php
 
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1. What is cold and cryogenic treating of steel?

Cold and cryogenic treating of steel is a process that involves subjecting steel to extremely low temperatures (below -100°C) in order to improve its physical and mechanical properties. This process is often used in the manufacturing of tools, knives, and other metal components to increase their durability and wear resistance.

2. How does the cold and cryogenic treating process work?

The process involves two main steps: cold treating and cryogenic treating. In cold treating, the steel is cooled to around -80°C using liquid nitrogen or other cryogenic gases. This causes the steel's molecular structure to rearrange, making it more dense and increasing its strength. In cryogenic treating, the steel is then further cooled to around -196°C, which helps to transform any remaining austenite into martensite, a harder and more wear-resistant form of steel.

3. What are the benefits of cold and cryogenic treating of steel?

Cold and cryogenic treating can significantly improve the strength, durability, and wear resistance of steel. It also helps to reduce the risk of cracking, warping, and other forms of damage that can occur during the manufacturing process. Additionally, this process can enhance the steel's ability to retain its sharpness and edge, making it ideal for use in cutting tools and knives.

4. Is cold and cryogenic treating suitable for all types of steel?

No, this process is not suitable for all types of steel. It is most commonly used on high-carbon and tool steels, as well as some stainless steels. The success of the treatment also depends on the quality and composition of the steel, as well as the specific temperature and duration of the treatment.

5. Are there any drawbacks to cold and cryogenic treating of steel?

The main drawback of this process is the cost. The equipment and materials required for cold and cryogenic treating can be expensive, making it a more costly option compared to other types of heat treatment. Additionally, if not done properly, the treatment can cause brittleness in the steel, reducing its toughness and impact resistance.

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