Laser Induced Breakdown Spectroscopy

In summary, the absence of oxygen lines in metal oxides spectrum taken at 532nm wavelength of Nd:YAG laser at atmospheric pressure could be due to oxygen in the atmosphere reabsorbing photons. The flux from the sample, distance to and sensitivity of the spectrometer setup may also play a role. Additionally, self absorption increases in the UV range where oxygen spectrum lies, and the air near the plasma may also absorb the radiations. The criteria for selecting emission lines for analysis would depend on these factors and the expertise of a spectroscopist.
  • #1
Farah Ikram
3
0
my question is why oxygen lines does not appear in metal oxides spectrum taken at 532nm wavelength of Nd:YAG laser at atmospheric pressure. and what is the criteria for selecting emission lines for analysis?
 
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  • #2
Maybe it's oxygen in the atmosphere is reabsorbing those photons?

It would depend on the flux coming from your sample and the distance to and sensitivity of your spectrometer set up.

There might be a more obvious reason, I'm no spectroscopist.
 
  • #3
you may be right...i'm thinking about the same reason becuase the self absorption increases in the UV range and oygen spectrum lies in the UV...another thing is that may be the air itself gets too thick near plasma it may also absorb the radiations as u have said
 

What is Laser Induced Breakdown Spectroscopy (LIBS)?

Laser Induced Breakdown Spectroscopy (LIBS) is an analytical technique used to identify and quantify the elemental composition of a sample. It involves focusing a high-powered laser onto the sample, which causes the sample to emit light. This light is then collected and analyzed to determine the elements present in the sample.

How does LIBS work?

In LIBS, a high-powered laser is focused onto a small area of the sample. The intense heat from the laser vaporizes the sample, creating a plasma. This plasma emits light at various wavelengths, which can be analyzed to determine the elemental composition of the sample.

What are the advantages of using LIBS?

LIBS has several advantages, including its ability to analyze a wide range of sample types, its non-destructive nature, and its fast analysis time. It also does not require any sample preparation, making it a convenient and cost-effective technique.

What are some applications of LIBS?

LIBS has a variety of applications in fields such as environmental monitoring, material analysis, and forensics. It can be used to analyze the composition of rocks, identify pollutants in water and soil, and even detect the presence of hazardous materials.

What are the limitations of LIBS?

One limitation of LIBS is its inability to detect elements that have a low atomic number, such as hydrogen and helium. It also has difficulty in distinguishing between elements with similar atomic masses. Additionally, the accuracy of LIBS can be affected by factors such as sample matrix and laser intensity.

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