What are the sign conventions for force in physical chemistry?

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In summary, force in physical chemistry has sign conventions that depend on the direction of the force and other conditions. Tension is positive while compression is negative. Force in the direction of motion is positive while force opposite the direction of motion is negative. For pressure, force in the direction of the surface normal is positive while force opposite the surface normal is negative. These conventions are important to understand in order to accurately calculate forces and accelerations in physical chemistry.
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hackerdiety03
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hey there! i am taking a physical chemistry course at my college. an assignment given was about miniature machines: "pulling" nanowires. one of the questions asked is concerning the types of sign conventions of force. i have tried to research this topic had have trouble finding out the different sign conventions. help!
 
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  • #2
Tension is considered positive, compression negative.

Force in the direction of motion is positive, force opposite direction of motion is considered negative.

Think of [itex]F = m \ddot{x} [/itex]

Positive F should yield positive acceleration, negative force yields deceleration.

With respect to pressure (force per unit area), force in direction of surface normal would be positive, force opposite direction of normal would be negative.
 
  • #3
so these are considered the sign conventions of force? the positive/negative signs depending on the direction of the force of the object and other conditions?
 
  • #4
Basically, yes.

Force and acceleration are vector quantities - and being so, they have magnitude and direction. The magnitude is always positive. The use of (+) and (-) relates to the direction in which the force is applied.
 

What is a force sign convention?

A force sign convention is a set of rules used to define the signs (+ or -) of forces in a given direction. This convention is used to determine the direction of forces in a specific problem and to ensure consistent calculations.

Why is the force sign convention important?

The force sign convention is important because it helps to clarify the direction and magnitude of forces in a problem. It also ensures that calculations are consistent and accurate, as forces can cancel each other out if their signs are not properly defined.

What are the three rules of the force sign convention?

The three rules of the force sign convention are: 1) forces acting in the same direction as the chosen positive direction are positive, 2) forces acting in the opposite direction to the positive direction are negative, and 3) forces acting perpendicular to the chosen positive direction have no sign.

How do you determine the positive direction in the force sign convention?

The positive direction is typically defined as the direction in which an object is moving or accelerating. If an object is not moving or accelerating, the positive direction can be arbitrarily chosen. It is important to be consistent in defining the positive direction throughout a problem.

Can the force sign convention be used for all types of forces?

Yes, the force sign convention can be used for all types of forces, including gravitational, frictional, and normal forces. It is important to properly define the positive direction for each force in order to accurately apply the convention.

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