The solution to the Shordinger's eq.

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In summary, the book of quantum mechanics by Griffiths states that the wave function must decay faster than 1/(|x|^-(1/2)) as |x| -> infinity. This is necessary for the wave function to have a statistical interpretation and be square integrable. The specific rate of decay depends on the potential, with a decreasing potential resulting in a plane wave solution and an increasing potential resulting in a slower decay. The general proof for this is complex and can be found in 'The Schrödinger Equation' by Berezin & Shubin.
  • #1
rbwang1225
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When I read the book of quantum mechanics of Griffiths, he said that the wave function must go to zero faster than 1/(|x|^-(1/2)), as |x| ->infinity. I wonder why?
Any help would be appreciated.
 
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  • #2
Because the wavefunction has the statistical interpretation that

[tex]
\int_{-\infty}^{+\infty} | \psi(x,t) |^2 d^3 x = 1
[/tex]

So psi has to be square integrable to make sense as a probability density.
 
  • #3
It depends on the potential, for a decreasing potential the wave function has plane wave type solution as |x| -> infinity, for increasing potential the wave function decreases at a rate depending on how fast the potential is increasing.

The general proof is quite subtle, eg see 'The Schrödinger Equation' - Berezin & Shubin , Kluwer Academic Publishers 1991.

I assume Griffiths had a specific potential function in mind.

(Square Integrable doesn't imply decreasing at infinity, although the counter examples are rather artificial mathematical constructs, and probably not physically interesting)
 

1. What is Schrodinger's equation?

Schrodinger's equation is a mathematical formula that is used to describe the behavior of quantum particles, such as electrons. It is a fundamental equation in quantum mechanics and is used to calculate the probability of finding a particle in a particular location at a given time.

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The solution to Schrodinger's equation provides information about the energy levels and possible states of a quantum system. This can help scientists to understand and predict the behavior of particles at the atomic and subatomic level.

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Schrodinger's equation is a fundamental equation in quantum mechanics, but it does have some limitations. It cannot be used to describe systems at extremely high energies, such as those found in particle accelerators, and it does not account for the effects of relativity. Additionally, it is a non-relativistic equation, meaning it does not work for particles traveling at close to the speed of light.

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