Why can no other engine be more efficient than a Carnot engine?

In summary, the conversation discusses the concept of the Carnot engine and how it is the most efficient engine. This is proven by imagining two heat engines, one being a Carnot engine with efficiency eC and the other being more efficient with efficiency e. The text explains that the more efficient engine would be able to drive the Carnot engine as a refrigerator, resulting in a transfer of energy from the cold to the hot reservoir without work being done. This goes against the Clausius statement of the second law, making it impossible for an engine to have an efficiency greater than a Carnot engine.
  • #1
member 392791
Hello,

I am having difficulty understanding the paragraph in my textbook explaining why no other engine can be more efficient than a carnot engine. What does it mean?

To prove the validity of this theorem, imagine two heat engines operating
between the same energy reservoirs. One is a Carnot engine with efficiency eC, and
the other is an engine with efficiency e, where we assume e > eC. Because the cycle
in the Carnot engine is reversible, the engine can operate in reverse as a refrigerator.
The more efficient engine is used to drive the Carnot engine as a Carnot refrigerator.
The output by work of the more efficient engine is matched to the input by
work of the Carnot refrigerator. For the combination of the engine and refrigerator,
no exchange by work with the surroundings occurs. Because we have assumed the
engine is more efficient than the refrigerator, the net result of the combination is
a transfer of energy from the cold to the hot reservoir without work being done on
the combination. According to the Clausius statement of the second law, this process
is impossible. Hence, the assumption that e > eC must be false.
 
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  • #2
It means that no engine can be more efficient than a Carnot engine. Such a machine could be used to reduce entropy (move energy from cold to hot reservoir), as shown in the text.
 
  • #3
That paragraph assumes in advance that the Clausius statement of the second law is valid, i.e. it is impossible to transfer energy from a cold reservoir to a hot one without an input of work. It then uses the method of contradiction to prove that no heat engine can have an efficiency greater than that of a Carnot engine. That is, we imagine that such an engine exists, and show that it would allow us to violate the Clausius statement.
 

1. Why is a Carnot engine considered to be the most efficient engine?

A Carnot engine is considered to be the most efficient engine because it operates on the Carnot cycle, which is a theoretical thermodynamic cycle that represents the maximum possible efficiency for a heat engine. This means that no other engine can surpass the efficiency of a Carnot engine.

2. What factors contribute to the efficiency of a Carnot engine?

The efficiency of a Carnot engine depends on the temperature difference between the hot and cold reservoirs, as well as the type of working fluid used. A higher temperature difference and an ideal gas as the working fluid can lead to a more efficient Carnot engine.

3. Can the efficiency of a Carnot engine be improved?

No, the efficiency of a Carnot engine cannot be improved. It represents the theoretical maximum efficiency for a heat engine, and any real engine will always have a lower efficiency due to various factors such as friction and heat loss.

4. Are there any real-life examples of a Carnot engine?

While there are no engines that operate on the Carnot cycle, the principles of the Carnot engine can be seen in some real-life systems such as refrigerators and heat pumps. These systems use the same principle of heat transfer between hot and cold reservoirs but in reverse to achieve cooling.

5. What are the limitations of a Carnot engine?

The main limitation of a Carnot engine is that it is a theoretical concept and cannot be fully realized in a real engine. Additionally, it assumes that the working fluid goes through reversible processes and does not account for factors such as friction and heat loss, which decrease the efficiency of real engines.

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