Silver as an electrode

by Fezziwig
Tags: electrode, silver
Fezziwig is offline
Sep7-13, 07:03 AM
P: 14
If I was to electrolyse a hot sodium chloride solution I'm pretty sure a copper electrode would react to make copper chloride. Whereas I would have used graphite electrodes if the solution was cold, this reaction should produce sodium chlorate which can obviously be quite reactive with organic compounds. The only other thing I have in the house is some spare silver. It's no platinum but it is more inert than copper. Would silver or graphite be safe, or should I only attempt this with platinum?
Phys.Org News Partner Chemistry news on
First view of nature-inspired catalyst after ripping hydrogen apart provides insights for better, cheaper fuel cells
Following a protein's travel inside cells is key to improving patient monitoring, drug development
Team helps cancer treatment drugs get past their sticking point
Borek is offline
Sep7-13, 09:09 AM
Borek's Avatar
P: 22,710
Silver is not that noble, especially in the chlorides solution it can be relatively easy oxidized to AgCl.
eigenperson is offline
Sep9-13, 10:28 PM
P: 133
What are you actually trying to do here?

Neither the oxygen gas nor sodium chlorate in aqueous solution, even at 100 degrees, should start a fire with your graphite electrode. Graphite requires very high temperatures to ignite.

Register to reply

Related Discussions
Difference between 2-electrode and 3-electrode cell Classical Physics 0
An electrolysis reaction: Silver electrode and cathode, Rochelle Salt solution Chemistry 3
To test the stability of a reference electrode in a 3 electrode setup Chemistry 0
electric double layer near electrode and electric field between electrode Classical Physics 2
Cylindrical electrode to rectangular electrode General Physics 0