Looking for Layman's Physical Explanation for energy level in atoms

In summary: But you are applying apples to oranges here. You can't use the SHO potential to an atom. That's just the wrong potential, so the...
  • #1
feynmann
156
1
I'm looking for a simple physical explanation of the discrete energy level in atoms, so I can provide a brief explanation to interested laypeople (not to mention just to help myself understand better). Does anybody want to take a crack at it? Or am I asking for the impossible?
 
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  • #2
The simplest model used to describe the energy levels in atoms is the Bohr model. You can find this by googling it or in elementary physics or chemistry texts. Be advised that the model sacrifices accuracy for simplicity...in general, as the models become more and more accurate they become more and more complex.
 
  • #3
Renge Ishyo said:
The simplest model used to describe the energy levels in atoms is the Bohr model. You can find this by googling it or in elementary physics or chemistry texts. Be advised that the model sacrifices accuracy for simplicity...in general, as the models become more and more accurate they become more and more complex.


Bohr claimed energy levels are quantized in atom. But I think Bohr's argument is wrong and circular, since he assumed that angular momentum is quantized in the first place, without any justification
 
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  • #4
feynmann said:
Bohr claimed energy levels are quantized in atom. But I think Bohr's argument is wrong and circular, since he assumed that angular momentum is quantized in the first place, without any justification

The justification is that it fits experiments.
 
  • #5
dx said:
The justification is that it fits experiments.

At that time, experiments justify the quantization of energy, but not the quantization of the electron's orbital angular momentum. In fact, the electron's orbital angular momentum is zero in the ground state of hydrogen atom.
Bohr model fall apart when the angular momentum is zero
 
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  • #6
feynmann said:
I'm looking for a simple physical explanation of the discrete energy level in atoms, so I can provide a brief explanation to interested laypeople (not to mention just to help myself understand better).

If your audience is acquainted with musical instruments and the concept of harmonics for a vibrating string or air column or drumhead, you can make an analogy with that. Just like vibrating strings etc. have discrete standing-wave modes which produce the harmonics, the QM wave function of a bound system has discrete standing-wave modes which produce the energy levels.
 
  • #7
The justification is that it fits experiments.

Yup, without this sort of justification quantum theory would be screwed.

The Bohr model has its shortcomings, but contains many of the basic concepts of quantum theory that still are present in the more advanced theories in modified forms (it introduced the very concept of quantized angular momentum that was carried over into later theories). The main failure of this model is that it restricts the movement of the electrons around the nucleus too rigidly compared to the models that followed.

If you really don't like it you can take a shot at a "layperson version" of the Shrodinger Equation with standing waves on a rope or guitar strings and such, but I personally wouldn't take this route unless my audience understood the Bohr model first (that's because I am not a big fan of "failing").
 
  • #8
Renge Ishyo said:
Yup, without this sort of justification quantum theory would be screwed.

The Bohr model has its shortcomings, but contains many of the basic concepts of quantum theory that still are present in the more advanced theories in modified forms (it introduced the very concept of quantized angular momentum that was carried over into later theories). The main failure of this model is that it restricts the movement of the electrons around the nucleus too rigidly compared to the models that followed.

If you really don't like it you can take a shot at a "layperson version" of the Shrodinger Equation with standing waves on a rope or guitar strings and such, but I personally wouldn't take this route unless my audience understood the Bohr model first (that's because I am not a big fan of "failing").
I think you miss the point. Bohr model fail miserably if you apply it to simple harmonic oscillator. Since angular momentum is zero in SHO but energy is still quantized, so angular momentum can Not be the reason for energy quantization
 
  • #9
I think you miss the point. Bohr model fail miserably if you apply it to simple harmonic oscillator. Since angular momentum is zero in SHO but energy is still quantized, so angular momentum can Not be the reason for energy quantization

I thought your goal was to give a simple introduction to the energy levels in atoms? Maybe I did miss the point...
 
  • #10
feynmann said:
I think you miss the point. Bohr model fail miserably if you apply it to simple harmonic oscillator. Since angular momentum is zero in SHO but energy is still quantized, so angular momentum can Not be the reason for energy quantization

But you are applying apples to oranges here. You can't use the SHO potential to an atom. That's just the wrong potential, so the argument that it doesn't work because the angular momentum is zero is moot.

I do not advocate using the Bohr model. However, there are many who still view them as an effective teaching method and argued that if done properly, may in fact serves its purpose. See, for example, http://prst-per.aps.org/pdf/PRSTPER/v4/i1/e010103" [Broken].

Zz.
 
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  • #11
ZapperZ said:
But you are applying apples to oranges here. You can't use the SHO potential to an atom. That's just the wrong potential, so the argument that it doesn't work because the angular momentum is zero is moot.

I do not advocate using the Bohr model. However, there are many who still view them as an effective teaching method and argued that if done properly, may in fact serves its purpose. See, for example, http://prst-per.aps.org/pdf/PRSTPER/v4/i1/e010103" [Broken].

Zz.

Pauli once remarked sadly 'That's not right. It's not even wrong, your theory make no prediction'". In a certain sense, the prediction of Bohr theory is very limited. It can apply only to one electron atom like hydrogen. It's just a collection of some ad hoc rules of quantization
 
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  • #12
feynmann said:
Pauli once remarked sadly 'That's not right. It's not even wrong, your theory make no prediction'". In a certain sense, the prediction of Bohr theory is very limited. It can apply only to one electron atom like hydrogen. It's just a collection of some ad hoc rules of quantization

That's fine. Like I said, I don't advocate using it. But don't use the SHO as the reason.

Zz.
 
  • #13
ZapperZ said:
That's fine. Like I said, I don't advocate using it. But don't use the SHO as the reason.

Zz.

Why not? Don't tell me what to do or what not to do!
If you know the answer, why don't you spell it out for us?
My guess is that you probably don't have an answer
 
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  • #14
feynmann said:
I think you miss the point. Bohr model fail miserably if you apply it to simple harmonic oscillator. Since angular momentum is zero in SHO but energy is still quantized, so angular momentum can Not be the reason for energy quantization

Isn't the Bohr model related to Somerfeld quantization which gives the SHO correctly?
http://en.wikipedia.org/wiki/Old_quantum_theory
http://people.ccmr.cornell.edu/~muchomas/8.04/Lecs/lec_bohr-sommerfeld/notes.html

I know the theory has been superseded - but Schroedinger was superseded by the Dirac wave equation which was superseded by QFT - so there is always another level, and Bohr was historically important and the idea of discrete energy levels being determined by boundary conditions on the wave solution carries over to Schroedinger.
 
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  • #15
feynmann said:
I'm looking for a simple physical explanation of the discrete energy level in atoms, so I can provide a brief explanation to interested laypeople (not to mention just to help myself understand better). Does anybody want to take a crack at it? Or am I asking for the impossible?
In all seriousness, it depends upon what you mean by "physical explanation". Please elaborate upon what you think that means to the intended lay person audience?
 
  • #16
feynmann said:
Why not? Don't tell me what to do or what not to do!
If you know the answer, why don't you spell it out for us?
My guess is that you probably don't have an answer

What did you think that I did in Post #10 already?!

I clearly explained why using the SHO potential is clearly irrelevant here in arguing why the Bohr model doesn't work! And did you even READ the link that I gave? How much more spoon-feeding do you need?

Zz.
 
  • #17
Let me follow this veering off the topic to the virtues or otherwise of teaching the Bohr model
feynmann said:
In a certain sense, the prediction of Bohr theory is very limited. It can apply only to one electron atom like hydrogen. It's just a collection of some ad hoc rules of quantization


Only by the very high standards of fundamental physics. In any other science the Bohr model would count as an incredibly compact condensate into a very few postulates.

Surely never has Science owed so much to so short-lived a theory!? To anyone who says it is only of historical interest I would answer yes it is of little interest if Science teaching is only about teaching technicians how to get right answers.

One advantage of having relatively elementary students go through proofs of Bohr type calculations is simply because they can!

Quote from Bohm
"Where the theory was in error, however, it was seldom very much so; hence it was clearly on the right track."
 
  • #18
epenguin said:
Let me follow this veering off the topic to the virtues or otherwise of teaching the Bohr model

Only by the very high standards of fundamental physics. In any other science the Bohr model would count as an incredibly compact condensate into a very few postulates.

Surely never has Science owed so much to so short-lived a theory!? To anyone who says it is only of historical interest I would answer yes it is of little interest if Science teaching is only about teaching technicians how to get right answers.

One advantage of having relatively elementary students go through proofs of Bohr type calculations is simply because they can!

Quote from Bohm
"Where the theory was in error, however, it was seldom very much so; hence it was clearly on the right track."

There is a problem though, in the sense that if this is not done properly (see the article I cited), you could end up with giving the students the wrong information that tend to live with them for the rest of their lives. Unfortunately, and anyone who has been on PF for any considerable amount of time can testify, this wrong idea about the atom has persisted for a large portion of the population. So essentially we are teaching them about "Santa Claus" (which, after all at that time, had its purposes), and no one told them when they grew up and it really doesn't exist.

We don't teach students about the Caloric theory and all the other now-erroneous ideas of physics, regardless of their historical significance or whether they were on "the right track". While the Bohr model can be useful in a limited range of cases, it creates way too much issues and problems that I don't see it as being worthwhile. The benefits here do not outweigh the problems. This is especially true if the instructor does not follow through and later on, correct the Bohr model and not leave the students hanging with the wrong picture.

Zz.
 
  • #19
For didactics I can see arguments on both sides, and in the teaching as in history it would have to be a brief passage.

If you are teaching the majority of general students, not destined to become professional physicists, about what Science is and its development, then the passages are almost if not equally as important as the arrival points?
 
  • #20
epenguin said:
For didactics I can see arguments on both sides, and in the teaching as in history it would have to be a brief passage.

If you are teaching the majority of general students, not destined to become professional physicists, about what Science is and its development, then the passages are almost if not equally as important as the arrival points?

Just to be clear, I am less concerned about teaching the Bohr model to physics students than I am to students that will not pursue a physics degree. Physics majors, sooner or later, will see the error in the Bohr model. Non-physics students do not, and if we stop at teaching them with the Bohr model, they are left "hanging" as I've said before, and stopped at an erroneous idea about the atom. That, to me, is unacceptable. No one corrected them that there's no Santa Claus.

Zz.
 
  • #21
feynmann said:
I'm looking for a simple physical explanation of the discrete energy level in atoms, so I can provide a brief explanation to interested laypeople (not to mention just to help myself understand better). Does anybody want to take a crack at it? Or am I asking for the impossible?


Im pretty familiar with converting science into common language .. and really do not see a significant problem with your task , except that is understanding the task itself .


Can you clarify ..

1. What discrete energy levels are you wanting to convey ? - please be explicit and definitive .

The improbable we can do immediately .. the impossible is done overnight :)
 
  • #22
I don't think the Bohr model is like Santa Claus (in the sense that it is not totally fabricated), there are many elements of the theory that still carry over into the more "advanced" models with only minor conceptual tweaks. Among the concepts that are carried over into advanced models are quantized angular momentum, emission and absorption of photons, discontinuous energy levels, stationary states, etc. The Bohr model helps build a "sense" of what these things mean even if the model is too simple to be completely true. It still predicts and explains the spectrum of hydrogen, and is a useful starting point for the Shrodinger wave mechanics as that study linked to before showed. I mean what would be a satisfying alternative, to go straight from the plum pudding model to matrix mechanics?

True a lot of people never get past the Bohr model. That is because the Bohr model represents the most fundamental level of physics that someone can seriously hope to study with only basic mathematics. Removing it wouldn't increase the amount of students who know differential equations so that they can study wave mechanics...it would simply decrease the amount of students who have any idea about what an atom is.

Rather than Santa Claus, I liken the Bohr model to something more like Disneyland. It's sort of a simplified idealistic fantasy imitation of atomic physics that's non-threatening and easy enough for beginners to understand, just as Disneyland is a fantasy imitation of the world that is easy to understand and non-threatening to kids. Later you find out about things like entanglement, non-locality, and sweat shops overseas producing Disney merchandise but by the time a person gets that far they will hopefully be able to handle it.
 
  • #23
feynmann said:
I'm looking for a simple physical explanation of the discrete energy level in atoms, so I can provide a brief explanation to interested laypeople (not to mention just to help myself understand better). Does anybody want to take a crack at it? Or am I asking for the impossible?

I write simulation software.

For discrete energy levels in a hydrogen gas, the picture I animate is at http://en.wikipedia.org/wiki/User:Edguy99#Discrete_energy_levels_-_The_hydrogen_spectrum
 
  • #24
Renge Ishyo said:
and sweat shops overseas producing Disney merchandise but by the time a person gets that far they will hopefully be able to handle it.

Whaaa... that's much worse than no Santa :cry:
 

1. What is the energy level in atoms?

The energy level in atoms refers to the specific amount of energy that an electron possesses while orbiting the nucleus of an atom. These energy levels are quantized, meaning they can only exist at certain discrete values.

2. How is the energy level in atoms determined?

The energy level in atoms is determined by the distance of the electron from the nucleus. The closer an electron is to the nucleus, the lower its energy level. This is because the nucleus exerts a strong attractive force on the electron, causing it to lose energy as it orbits.

3. What is the significance of energy levels in atoms?

The energy levels in atoms are significant because they determine the chemical and physical properties of elements. The arrangement of electrons in different energy levels is what gives elements their unique characteristics, such as reactivity and conductivity.

4. Can energy levels in atoms change?

Yes, energy levels in atoms can change. When an atom absorbs or releases energy, its electrons can jump to a higher or lower energy level. This is known as an electron transition, and it is what gives rise to phenomena like emission spectra.

5. How are energy levels in atoms related to the electromagnetic spectrum?

The energy levels in atoms are directly related to the electromagnetic spectrum. When electrons transition between energy levels, they emit or absorb energy in the form of electromagnetic radiation. This radiation can range from radio waves to gamma rays, with each type corresponding to a specific energy level transition.

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