Understanding 2 Adiabatic Processes and the 2nd Law of Thermodynamics

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In summary, the 2nd law of thermodynamics states that the net work done on a system is equal to the heat entering the system minus the heat leaving the system. This explains why two adiabatic processes cannot intersect on a PV diagram when connected by an isothermal process. However, the question arises as to why this law holds true without a statistical approach. The answer lies in the fact that heat flow is necessary for work to be produced in an engine, which is essentially a restatement of the conservation of energy. Heat is defined as the energy transfer due to a difference in temperature, but temperature itself is a statistical concept. Without taking into account statistical physics, the idea of heat and its relationship to work becomes nonsensical
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orthovector
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If you accept that the 2nd law of thermo tells you that the

[tex] Work_{net} = Q_{in} - Q_{out} [/tex]

it's easy to see why 2 adiabatic processes cannot cross on a PV diagram when connected by an isothermal process.

however, why is the 2nd law true without taking a statistical approach?
Why must we have heat flow in order to get work out of an engine?
 
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  • #2
isn't that a restatement of the conservation of energy?
 
  • #3
how do you define heat? in wikipedia it says "the energy transfer due to a difference in temperature", and temperature is a statistical definition. so there would be no sense to state such a law without the statistical approach.
 
  • #4
you mean to tell me you cannot explain why 2 adiabatic processes cannot cross without doing a statistical approach to temperature?

I'm sure one can explain why heat flow is necessary for work inside an engine without statistics.

I haven't gotten to statistical and thermal physics yet...
 
  • #5
no, what I'm telling you is that in order to define heat, you need to define temperature, and temperature is just a way of forgetting about certain degrees of freedom and collapse them into what we call 'temperature'. So to define adiabatic, you need to define heat, so you need to define temperature, and to do this, you collapse this whole mess of particles interacting with each other into one statistical definition, which is i think, the average kinetic energy or something like that.
that is, heat makes no sense at all just like friction makes no sense at all when you are taking into account every degree of freedom your system has.

EDIT: i haven't got to statystical physics yet neither.
 

1. What is an adiabatic process?

An adiabatic process is a thermodynamic process in which there is no heat exchange between the system and its surroundings. This means that the system is insulated and cannot exchange energy with its surroundings through heat transfer. Adiabatic processes are often used to analyze the behavior of gases.

2. What is the second law of thermodynamics?

The second law of thermodynamics states that the total entropy of an isolated system always increases over time, or remains constant in ideal cases where the system is in a steady state or undergoing a reversible process. This law is used to explain the direction of energy flow and the irreversibility of many natural processes.

3. How are adiabatic processes related to the second law of thermodynamics?

The second law of thermodynamics implies that in an adiabatic process, the total entropy of the system must increase or remain constant. This means that heat energy cannot be completely converted into work, and some amount of energy will always be lost as heat. Adiabatic processes can be used to illustrate the limitations of the second law of thermodynamics.

4. How do we calculate the change in entropy for an adiabatic process?

The change in entropy for an adiabatic process can be calculated using the equation ΔS = nCvln(T2/T1), where n is the number of moles of gas, Cv is the heat capacity at constant volume, T2 is the final temperature, and T1 is the initial temperature. This equation assumes that the process is reversible and that the heat capacity remains constant over the temperature range.

5. Can an adiabatic process be completely reversible?

No, an adiabatic process cannot be completely reversible. This is because the second law of thermodynamics dictates that some energy will always be lost as heat, resulting in an increase in entropy. However, adiabatic processes can be made more reversible by minimizing energy losses and using insulating materials to reduce heat transfer.

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