Why is the flow behaviour or viscosity important in the case of polymer?

In summary, the flow behaviour and viscosity of polymers are important characteristics as they provide information about the structure and bonding of the polymer, as well as its processibility for various applications. In a physical chemistry lab, it was demonstrated that the molecular weight of a polymer can be derived from its viscosity coefficient. The viscosity is also influenced by the tightness of the molecular coils.
  • #1
cutepig
1
0
Why is the flow behaviour or viscosity important in the case of polymer?

This question is given when we had lecture about flow behaviour, viscosity, and rheology.

Thanks a lot!
 
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  • #2
Viscosity is an important characteristic of polymers because it gives an insight to the structure and in turn, the degree of bonding in the structure, and how well the structure is formed. Flow behaviour determines the processibility of the polymer into different products like plastics, elastomers etc It's atill an important research area as to how to manipulate polymers for various applications.

E.g. of such applications http://www.phy.bris.ac.uk/research/polymers/flow.html
 
  • #3
Mr.cute, are you a student taking course MAT705 in Queen Mary College? I meet the same question in the exam.
 
  • #4
Well, in a physical chemistry lab this semester we dissolved polystyrene in toluene and measured the viscosity, from which we were able to derive the molecular weight of the polymer from the relationship n = M^a (where n is the viscosity coefficient, M was the molar mass and a was a constant equal to about ~0.75 if I remember correctly. We measured the molecular weight to about 100,000 g/mol, which was pretty accurate.

As atomic blast suggested, the viscosity is influenced by how tightly "coiled" the molecule is - that is what the consant "a" is a measure of.
 

1. Why is the flow behaviour or viscosity important in the case of polymer?

The flow behaviour or viscosity of a polymer is important because it affects its processing and application properties. The flow behaviour determines how easily a polymer can be melted, shaped, and formed into different products. The viscosity also affects the strength, flexibility, and durability of the final product.

2. How does the flow behaviour or viscosity of a polymer affect its processing?

The flow behaviour or viscosity of a polymer can significantly impact its processing. A high viscosity polymer will require more energy and time to melt and shape, whereas a low viscosity polymer will melt and flow more easily. This can affect the production rate and cost of manufacturing products made from polymers.

3. What factors influence the flow behaviour or viscosity of a polymer?

The flow behaviour or viscosity of a polymer is influenced by several factors, including its molecular weight, molecular structure, temperature, and processing conditions. Polymers with longer chains and more complex molecular structures tend to have higher viscosities, whereas polymers with shorter chains and simpler structures have lower viscosities.

4. How does the flow behaviour or viscosity of a polymer affect its application properties?

The flow behaviour or viscosity of a polymer can greatly impact its application properties. For example, a high viscosity polymer will be more rigid and less flexible, making it suitable for applications that require strength and durability, such as in construction materials. On the other hand, a low viscosity polymer will be more fluid and flexible, making it suitable for applications that require flexibility, such as in packaging materials.

5. Can the flow behaviour or viscosity of a polymer be altered?

Yes, the flow behaviour or viscosity of a polymer can be altered through various methods, such as adding plasticizers or adjusting the processing conditions. Plasticizers can reduce the intermolecular forces and increase the molecular mobility, resulting in a lower viscosity. Changing the temperature or shear rate during processing can also affect the flow behaviour of a polymer. Additionally, blending different polymers can also alter the flow behaviour and viscosity of a polymer blend.

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