Band spectrum and line spectrum

In summary, atoms in excited state alone can emit line spectra because they have discrete energy levels. Molecules and atoms in a liquid state can emit band spectra because they have more energy levels available for accepting or giving up energy.
  • #1
smart_worker
131
1
why do the atoms in excited state alone could emit line spectra?can't they emit when they are not in gaseous state?

why only molecules can emit band spectra?can't atoms emit them
 
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  • #2
An isolated atom, such as one in a gaseous state, has only its atomic energy levels available to accept or give up energy. Since these energy levels are discrete, the light emitted by the atoms will also be in discrete wavelengths.

Atoms bound in molecules or in a liquid state have more energy levels to accept or give up energy from. As such, the light they emit will be over a much broader range. In an everyday solid or liquid the amount of energy levels is so large that light is emitted over the entire spectrum.
 

1. What is the difference between band spectrum and line spectrum?

Band spectrum refers to a continuous range of wavelengths of electromagnetic radiation emitted by a substance, while line spectrum refers to a series of distinct, discrete lines of different wavelengths emitted by an element or molecule.

2. How are band spectrum and line spectrum produced?

Band spectrum is produced when electrons in a substance are excited to higher energy levels, and then fall back to lower energy levels, releasing energy in the form of a continuous spectrum. Line spectrum is produced when electrons move between specific energy levels, emitting photons of specific wavelengths.

3. How can band spectrum and line spectrum be used in scientific research?

Band spectrum and line spectrum can be used to identify the elements or molecules present in a sample, as each has a unique spectral fingerprint. They can also provide information about the energy levels and electronic structure of these substances.

4. Can band spectrum and line spectrum be observed in everyday life?

Yes, both band spectrum and line spectrum can be observed in everyday life. For example, band spectrum can be seen in the colors of a rainbow, which is a continuous spectrum of visible light. Line spectrum can be seen in the colored lights emitted by neon signs, which contain specific gases that emit light at certain wavelengths.

5. What are some limitations of using band spectrum and line spectrum in scientific analysis?

One limitation is that band spectrum and line spectrum can only be observed for substances that emit or absorb electromagnetic radiation, which may not be applicable to all materials. Additionally, the accuracy of spectral analysis can be affected by factors such as impurities in the sample or instrumental limitations.

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