Ultraviolet Catastrophe / Rayleigh-Jeans Black Body Cavity

In summary, the "Ultraviolet Catastrophe" refers to a problem in dealing with black body radiation where the Rayleigh-Jean equation for energy density becomes infinite at ultraviolet frequencies and beyond. This is due to the fact that the classical analysis of the equation does not have an upper limit on frequency, leading to a divergence in the total energy when integrated over all frequencies. This problem was solved by Max Planck using quantum mechanics, which was initially seen as an adhoc curve fitting but later became accepted as a more accurate description of reality.
  • #1
mrjeffy321
Science Advisor
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In reading about the “Ultraviolet Catastrophe” in dealing with black body radiation, my book says that at the ultraviolet frequencies and beyond, the Rayleigh-Jean equation for the energy density of the radiation would be infinite (and thus a catastrophe).
If this is the Rayleign-Jeans equation:
p(v)dv = (8 * pi * v^2 * k * T * dv) / c^3
with v being the frequency of light…how does this number come out to be infinite at some finite frequency?
For example, 1 E16 Hz would be well within the ultraviolet part of the EM spectrum. If I plug this value into the above equation I will get a very large number to be sure, but it will not be infinity. Or do they just mean that as the frequency goes to infinity, so does the energy, when we know otherwise experimentally.
 
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  • #2
Objects don't radiate at a single frequency only. The problem is the total energy that you get when you integrate over all frequencies. In the classical Rayleigh-Jeans analysis, there's no upper limit on the frequency.
 
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  • #3
Correct, and its ironic in fact that quantum mechanics was given birth by the observation that you had to cut the divergence off in just about the most naive way imaginable to a theorist. So Planck basically curve fitted and found that the only way to do this was by adding an arbitrary h in integer units to the equation.

No one until Bohr believed for a second this adhoc curve fitting had anything to do with reality, except that it was a convenient semi empirical law, good for handwavey arguments. And then, even then, his model was quite obviously flawed so it took an extra 10 years (and many experiments) before people took it seriously and QM became accepted lore.
 
  • #4
OK, I see. Thanks.
 

1. What is the Ultraviolet Catastrophe?

The Ultraviolet Catastrophe, also known as the Rayleigh-Jeans Black Body Catastrophe, refers to a theoretical problem in the late 19th century where classical physics predicted an infinite amount of energy being emitted by a black body at short wavelengths. This was in direct contradiction to experimental results, leading to the development of quantum mechanics.

2. What is a black body?

A black body is an idealized object that absorbs all incoming electromagnetic radiation and emits radiation at all wavelengths. It is often used in physics as a theoretical model to understand how objects emit and absorb radiation.

3. What is the Rayleigh-Jeans law?

The Rayleigh-Jeans law was a classical physics equation developed by Lord Rayleigh and Sir James Jeans to describe the energy distribution of a black body. It predicted that the amount of energy emitted by a black body would increase infinitely as the wavelength decreased, leading to the Ultraviolet Catastrophe.

4. How did the Ultraviolet Catastrophe lead to the development of quantum mechanics?

The Ultraviolet Catastrophe highlighted a major flaw in classical physics and the need for a new understanding of the behavior of matter and energy at the atomic level. This led to the development of quantum mechanics, which explained the behavior of particles and energy at the subatomic level and resolved the contradiction between theory and experiment.

5. How does Planck's law resolve the Ultraviolet Catastrophe?

Max Planck's law, developed in 1900, introduced the concept of quantization and explained that energy is not emitted or absorbed continuously, but in discrete packets called quanta. This resolved the Ultraviolet Catastrophe by limiting the amount of energy that could be emitted at short wavelengths, bringing the predicted energy distribution in line with experimental results.

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