Reducing Iron Oxide with Methane

In summary: It is a mixture of iron and carbon. This mixture is too soft to be used for anything other than a casting material.
  • #1
JGM_14
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0
Can iron oxide be reduced to metallic iron with methane in place of hydrogen?
 
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  • #2
JGM_14 said:
Can iron oxide be reduced to metallic iron with methane in place of hydrogen?

What exactly does this question mean? In place of which hydrogen?

Are you trying to pull electrons from the methane and give them to the iron? I think doing that would create something like 2 methanols, or a methane diol, or formaldehyde and 2 hydrogen cations. None of these reactions sound reasonable, so I'll guess the answer is no.
 
  • #3
It depends on how you do it. If your process cracks the methane into hydrogen, it is possible. If the process is not controlled to do that, I believe that iron carbide will be formed.
 
  • #4
ShawnD said:
In place of which hydrogen?

Elemental hydrogen.
Fe2O3+3H2+heat=2Fe+3H2O
Can this be done- Fe2O3+CH4=Fe+H2O+CO2 (unbalanced)

chemisttree said:
It depends on how you do it. If your process cracks the methane into hydrogen, it is possible. If the process is not controlled to do that, I believe that iron carbide will be formed.
iron carbide= Steel, correct?
 
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  • #5
These guys claim to be able to do it using microwave treatment of iron oxide and natural gas. Its by Russians during the height of the cold war and I always treated those references with some skepticism..

http://www.springerlink.com/content/v114012j12u68705/

The usual product is iron carbide and magnetite. This is a typical application of a Fischer-Tropsch process. It allows one to convert gaseous hydrocarbons into liquid hydrocarbons. The Germans did this during the war to produce 'synthetic' fuels and lube oils. It is currently being used for the same purpose. It is a fairly expensive process but as the price of crude oil increases, it becomes ever more feasible from an economic standpoint.

iron carbide is not steel.
 

1. How does reducing iron oxide with methane work?

When methane (CH4) is passed over heated iron oxide (FeO), a reaction occurs where the methane molecules break down and react with the iron oxide to form iron (Fe), carbon dioxide (CO2), and water vapor (H2O). This process is known as reduction and results in the removal of oxygen from the iron oxide, leaving behind pure iron.

2. What is the purpose of reducing iron oxide with methane?

The purpose of this process is to produce pure iron for industrial purposes. Iron oxide is a common mineral found in ores, but it is not useful in its natural form. By reducing it with methane, the oxygen is removed and pure iron is produced, which can then be used for various applications such as manufacturing steel.

3. What are the necessary conditions for reducing iron oxide with methane?

The reaction between iron oxide and methane requires a high temperature (typically between 800-1000°C) and an oxygen-free environment. This can be achieved in a furnace or kiln where the mixture of iron oxide and methane is heated in the absence of oxygen.

4. Can other gases be used to reduce iron oxide?

Yes, other reducing agents such as hydrogen (H2) or carbon monoxide (CO) can also be used in place of methane. However, methane is often preferred due to its low cost and abundance.

5. Are there any environmental concerns with reducing iron oxide with methane?

While the reaction itself produces carbon dioxide, the use of methane as a reducing agent results in a net reduction in greenhouse gas emissions compared to traditional methods of producing iron. However, methane is still a potent greenhouse gas and any leaks or emissions during the process must be carefully monitored and controlled.

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