What does the ratio c/a mean in solid state phyiscs

In summary, the ratio c/a in solid state physics refers to the relationship between the elementary cell extension along the hexagonal axis (c) and the dimension along the hexagons (a). This ratio is important in hexagonal elemental systems because it affects the distances between atoms in the basal plane and between planes. The ideal ratio is around 1.63 and is derived through group theory, but for general crystals with a hexagonal lattice, there is no restriction on this ratio.
  • #1
j-lee00
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What does the ratio c/a mean in solid state physics?

I have attached a table with a an example.

Cheers
 

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  • #2
It stands for nothing special as long as you don't enlight us what a and c are abbreviations for.
Usually c is the elementary cell extension along the hexagonal axis and a is the dimension along the hexagons.
 
  • #3
The ratio c/a for a hexagonal elemental system is interesting because there is an ideal c/a ratio where the distance between every atom is the same. If c/a deviates from that value then the distances between nearest neighbor atoms in the basal plane is different than the distances between nearest atoms between planes. The ideal value is something like 1.63; it is a nice exercise to derive it yourself.
 
  • #4
Or to say it differently, there is the hcp structure of ideal spheres which a definite ratio of a/c. However, for a general crystal with a hexagonal lattice, group theory does not put any restriction on that ratio.
 

1. What is the significance of the ratio c/a in solid state physics?

The ratio c/a is a fundamental property of a crystal lattice, known as the axial ratio. It represents the relationship between the length of the unit cell along the c-axis and the length along the a-axis. This ratio is important in determining the symmetry and physical properties of a crystal.

2. How is the ratio c/a related to the crystal structure of a material?

The ratio c/a is directly related to the crystal structure of a material. It is used to classify different crystal systems, such as hexagonal, cubic, or tetragonal, based on the arrangement of atoms within the lattice. In addition, this ratio can also affect the mechanical, electrical, and thermal properties of a material.

3. What factors can influence the value of the ratio c/a?

The ratio c/a can be influenced by a variety of factors, such as temperature, pressure, and the chemical composition of the crystal. It can also be altered by defects or impurities within the crystal lattice. The ratio c/a can also change during phase transitions, where the crystal structure undergoes a transformation.

4. How is the ratio c/a measured in experiments?

The ratio c/a can be measured using various experimental techniques, such as X-ray diffraction or electron microscopy. These methods allow for the determination of the lattice parameters, including the lengths of the unit cell along the c-axis and a-axis, which can then be used to calculate the ratio c/a.

5. What are some practical applications of understanding the ratio c/a in solid state physics?

Understanding the ratio c/a is crucial in the design and development of new materials with specific properties. For example, in the field of materials science, this ratio can be used to predict the strength and stability of a crystal structure. It is also important in the study of crystal defects and their impact on the overall properties of a material.

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