What is the structure of NaN3? Why is N2 gas, and P solid at STP?

In summary, Malay asked two questions: 1) What is the structure of NaN3? and 2) Why is nitrogen gas whereas phosphorus is solid? They discussed the possibility of the bonding in NaN3 being ionic and the existence of intermolecular forces between nitrogen and phosphorus. It was determined that the difference in the number of atoms in each molecule and the larger size of the phosphorus molecule may contribute to the stronger van der Waal forces that cause it to exist in a solid state.
  • #1
MalayInd
33
0
Here are the two questions:
1)What is the structure of NaN3?
2)Why is nitreogen gas whereas phosphorus is solid?


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Malay
 
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  • #2
1. [itex][N=N=N]^- Na^+[/itex] (I goggled this.)
2. I don't know.
 
  • #3
Thanks.
What is the crystal structure, or what is the 3D structure.

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Malay
 
  • #4
Malay, when I answered your first question, it was before this thread was moved to the homework help area. In this area, we are requested not to give out answers, but to help you to find the answer yourself. What steps have you taken to find an answer, and what progress have you made?
 
  • #5
1)I was not able to find the bonding in NaN3 either by VB theory or by MO theory, but I guessed that it should be ionic and hence should have crystal structure.
2)I studied about existence of nitrogen molecules and phosphorus molecules but could not deduce anything relevant to the question.

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Malay
 
  • #6
What kind of intermolecular forces exist between Nitrogen and Phosphorous? Is it Van Der Waal? Permanent Dipoles? Ionic?
Well, i'll answer that... It's van der waal foces...
but what is the difference between these two molecules? of how much atoms does nitrogen consists and of how much atoms does phosphorous consist in one molecule?

If phosphorous exists in solid state, therefore, its van der waal forces should be stronger... what causes this? what increases the van der waal forces?
 
  • #7
I think taht large size of the phophorus molecule may increase the van der waals forces.

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Malay
 

What is the structure of NaN3?

The structure of NaN3, or sodium azide, is a linear molecule with a central nitrogen atom bonded to three sodium atoms on one side and a single nitrogen atom on the other side. The molecular formula is N3Na, and it is commonly used as a propellant in airbags.

Why is N2 gas at STP?

N2, or nitrogen gas, is a diatomic molecule that exists as a gas at standard temperature and pressure (STP) due to its low molecular weight and weak intermolecular forces. At STP, the molecules of N2 have enough thermal energy to overcome these weak forces and remain in the gas state.

Why is P solid at STP?

P, or phosphorus, is a nonmetal element that exists as a solid at STP due to its relatively high atomic weight and strong intermolecular forces. These forces are strong enough to keep the molecules of P in a solid state at STP despite the thermal energy present.

Why does NaN3 have a linear structure?

The linear structure of NaN3 is a result of the bonding between the nitrogen and sodium atoms. Sodium has a single valence electron, which it donates to the nitrogen atom, forming a triple bond. This results in a linear arrangement of the atoms in the molecule.

What is the significance of NaN3's structure?

The linear structure of NaN3 is important for its use as an airbag propellant. When the compound is ignited, it rapidly decomposes into nitrogen gas, which rapidly expands, filling the airbag and providing a cushion for the passenger. The linear structure of NaN3 allows for a more efficient and rapid decomposition process.

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