Solubility for hydrated calcium sulfate in HCl

In summary, The solubility of hydrated calcium sulfate in HCl varies depending on the concentration of the acid. At low concentrations of HCl, the solubility is around 0.2 g/100 mL, but at higher concentrations, it can increase to 1.5 g/100 mL. The chemical equation for the reaction between hydrated calcium sulfate and HCl is CaSO4 · 2H2O + 2HCl → CaCl2 + SO2 + 2H2O. This limited solubility is due to the strong ionic bonds between calcium and sulfate ions, which can only be broken to a certain extent by the polar HCl molecule. Factors such as concentration, temperature, and the presence
  • #1
Kruz87
17
0
was asked to consider the solubility for hydrated calcium sulfate in HCl.
The principal acid my proffesor had posted for the solution was [ CaSO4(hyrdrated) + HCl <--> H30^+ + Ca^2+ + SO4^2- ]. I guess what I'm asking is what happened to the Cl^- and why isn't it reacting with Ca^2+ to produce CaCl2. ? It's not a spectator ion right? But if it is why?
 
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  • #2
Chlorides are soluble, and the chloride ion will remain freely ionized. The "calcium chloride" will be present as ions of Ca(+2) and Cl(-1)
 
  • #3


I would like to clarify that the reaction you have provided is not the solubility reaction for hydrated calcium sulfate in HCl. The solubility reaction would be written as CaSO4 (hydrated) + 2HCl → CaCl2 + H2SO4. This reaction indicates that hydrated calcium sulfate (CaSO4) reacts with 2 molecules of hydrochloric acid (HCl) to form calcium chloride (CaCl2) and sulfuric acid (H2SO4). The sulfuric acid may further dissociate to form H+ and SO4^2- ions.

Now, coming to your question about the role of chloride ions (Cl^-) in this reaction, they do not participate in the reaction itself but serve as a counterion to balance the charges of the resulting ions. Calcium chloride (CaCl2) is a salt that dissociates in water to form Ca^2+ and 2Cl^- ions, which can be considered as spectator ions in this reaction. They do not undergo any chemical changes and remain in solution.

I hope this clarifies your doubts about the role of chloride ions in the solubility reaction of hydrated calcium sulfate in HCl. it is important to carefully examine the chemical equations and understand the role of each component to accurately interpret the reactions.
 

What is the solubility of hydrated calcium sulfate in HCl?

The solubility of hydrated calcium sulfate in HCl varies depending on the concentration of the acid. At low concentrations of HCl, the solubility of hydrated calcium sulfate is around 0.2 g/100 mL. However, at higher concentrations of HCl, the solubility can increase up to 1.5 g/100 mL.

What is the chemical equation for the reaction between hydrated calcium sulfate and HCl?

The chemical equation for the reaction between hydrated calcium sulfate and HCl is CaSO4 · 2H2O + 2HCl → CaCl2 + SO2 + 2H2O.

Why does hydrated calcium sulfate have limited solubility in HCl?

Hydrated calcium sulfate, also known as gypsum, has limited solubility in HCl because of its strong ionic bonds. The HCl molecule is polar and can break apart the ionic bonds between calcium and sulfate ions, but only to a certain extent.

What factors can affect the solubility of hydrated calcium sulfate in HCl?

The solubility of hydrated calcium sulfate in HCl can be affected by several factors, such as the concentration of the acid, temperature, and the presence of other ions in the solution. Higher concentrations of HCl and higher temperatures can increase the solubility, while the presence of other ions can decrease it.

What are some practical applications of understanding the solubility of hydrated calcium sulfate in HCl?

Understanding the solubility of hydrated calcium sulfate in HCl is important in various industries, such as in the production of fertilizers and building materials. It is also useful in laboratory experiments, specifically in titrations and quantitative analysis of calcium sulfate in different solutions.

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