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First law of thermodynamics applied to Compression and Expansion

 
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Sep20-12, 03:14 PM   #1
 

First law of thermodynamics applied to Compression and Expansion


How does the first law of thermodynamics apply to the Compression And expansion of a gas at constant temperature ?

If the gas is at a constant temperature and is being compressed, then
ΔQ = 0
ΔU = +
W(on the system) = +


Are those(^^) correct ?

The equation being :
ΔU = ΔQ + W(on the system)
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Sep20-12, 03:26 PM   #2
 
Compression or expansion at constant temperature means heat is extracted or added.
Sep20-12, 03:27 PM   #3
 
At constant temperature ΔQ is not zero. ΔU is zero, for ideal gas.
Sep21-12, 12:59 AM   #4
 

First law of thermodynamics applied to Compression and Expansion


Quote by nasu View Post
At constant temperature ΔQ is not zero. ΔU is zero, for ideal gas.
would u explain "why" ?
Sep21-12, 02:35 AM   #5
 
would u explain "why" ?
Originally this was an experimental fact about gasses. Nowadays there is maths to back it up, and we know that it only applies to ideal or perfect gasses.




http://demonstrations.wolfram.com/Jo...FreeExpansion/

If you can cope with the maths google has lots on the Joule experiment and the Joule-Thompson experiment.

If not you can take it as a definition of a perfect gas.

The internal energy of a perfect gas depends only on its temperature.
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