Thermodynamics which equation is correct

In summary, the first law of thermodynamics states that energy cannot be created or destroyed, only transferred or converted. Its equation is ΔU = Q - W. The second law of thermodynamics states that the total entropy of an isolated system can never decrease over time, with its equation being ΔS ≥ Q/T. The ideal gas law, PV = nRT, combines fundamental principles of thermodynamics and is often used in calculations. There are two types of thermodynamic systems, open and closed, with open systems allowing for the exchange of matter and energy and closed systems only allowing for energy transfer. Thermodynamics is crucial in everyday processes such as cooking, refrigeration, and electricity generation, and also helps us understand the behavior of gases, liquids
  • #1
pokie_panda
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Homework Statement



Calculate the energy which has 15.5% occupancy probability for copper at T=295. Assume, Ef = 7.00eV for copper.

I seen two equations which one is correct

1
_____________
exp(E- Ef / kT)


or
1
_____________
1+(exp(E- Ef / kT))
 
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  • #2
That's a question you should be able to answer on your own. Neither of those is an equation as no equal sign appears anywhere. Where did you get these expressions from? What does your textbook say?
 

1. What is the first law of thermodynamics and its equation?

The first law of thermodynamics states that energy cannot be created or destroyed, only transferred or converted. The equation for this law is: ΔU = Q - W, where ΔU represents the change in internal energy, Q represents the heat added to the system, and W represents the work done by the system.

2. What is the second law of thermodynamics and its equation?

The second law of thermodynamics states that the total entropy of an isolated system can never decrease over time. The equation for this law is: ΔS ≥ Q/T, where ΔS represents the change in entropy, Q represents the heat added to the system, and T represents the temperature in Kelvin.

3. How is the ideal gas law related to thermodynamics?

The ideal gas law, PV = nRT, is a combination of Boyle's law, Charles's law, and Avogadro's law, which are all fundamental principles of thermodynamics. It relates the pressure, volume, temperature, and number of moles of an ideal gas and is often used in thermodynamics calculations.

4. What is the difference between an open and closed thermodynamic system?

An open thermodynamic system allows for the exchange of matter and energy with its surroundings, while a closed system only allows for the exchange of energy. In other words, an open system can have mass and energy flow in and out, while a closed system can only have energy transfer.

5. How does thermodynamics relate to everyday life?

Thermodynamics is essential in many everyday processes, such as cooking, refrigeration, and electricity generation. It also helps us understand the behavior of gases, liquids, and solids and their phase changes. Understanding thermodynamics can also aid in making more efficient and sustainable energy choices.

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