What happens to lead then you overhead it beyond its melting point

In summary: The fumes of this liquid are very poisonous. It forms an explosive gas on fire, which burns with a gray flame. The gas is heavier than air, and will sink to the bottom of a vessel. It is soluble in water and alcohol. A small quantity of the gas will cause suffocation in a person. Antimony is found in alloys and is used in plating and in the construction of watch springs. It is also used in the manufacture of fireworks and in the manufacture of some acids. The body becomes emaciated on over taking small quantities."In summary, lead melts when it is heated, and if you continue to heat it beyond its boiling point, you get
  • #1
Jacquesl
136
1
What happens to lead then you overheat it beyond its melting point, and what metal or chemical does it become then?
 
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  • #2
It becomes molten lead. If you continue to heat the liquid beyond its boiling point, you get lead vapor.
 
  • #3
So see then you heat lead and it melt then it makes like a bubble, it’s like mercury, but then you heat it to much then suddenly it drops down and becomes red almost like your heating iron or something and it’s strong but very brittle

What does this molten lead actually means, does it have a Molecular formula beside Pb
 
  • #4
does it make bubbles if it was heated in a vacuum?
 
  • #5
The chemical formula for water is H20, regardless of whether the water is ice, liquid, or steam. Why would you expect the frozen/liquid/vapor form of lead to have a different chemical formula? They are all lead.
 
  • #6
Well belief me that lead must have a dioxide after it or something, because it’s pretty much screwed, ash
 
  • #7
That makes absolutely no sense at all. Care to clarify?
 
  • #8
If you over heat lead over its melting point, it changes it self to some messed up substance, now that’s what I’m not sure of it’s like then you overheat Aluminium it does the same thing, it make some kind of substance.

It’s probably like Sulfur you can melt sulfur bit if you over heat it, it start to burn and produce Sulfur dioxide SO2
 
  • #9
If you got your "lead" from wheel weights or lead acid batteries, the hard brittle stuff left over when you distill out the lead is antimony. Antimony is hard, silver to gray and brittle. It will cause contact dermatitis, conjunctivitus (pink eye), nasal ulceration. Bad JU JU! Keep it away from any of your hydrogen experiments since it will form extremely toxic, volatile hydrides.

Find the Merck Index at your local College library and make friends with it.

Just a note... I hope that when you are doing this kind of stuff you aren't inhaling or you are using a good hood. A garage with a few open doors really won't cut it.
 
  • #10
I've cast both lead and aluminum, but I've never taken them very much past their melting points. Are you (jacques) talking about the layer of dross that forms over the melt? That, as you guessed, is predominantly the oxide of the metal, but also includes other impurities (as pointed out by c-tree). If you skim off the dross, you have nice, clean melt below.
 
  • #11
I have ran Al way past its melting point (~900C) IIRC we saw no strange material form. How hot are you talking about. The more specifics you can provide the better.

You may be reacting with your crucible, with the atmosphere and/or with any impurities in the original metal. There is no way we could tell what he dross is since you have not provided even the basic info needed.
 
  • #12
~1700C but this is done by a oxy-torch, it starts to make white sparks, but never mind that, it just basically starts to ignite the Al, but I’m more into the lead one, did you test out the lead ?
 
  • #13
Gokul43201, I think you understand my setup, Yip I’m Jacques, my lead is almost pure lead, it’s in a bars, I’ve found 3 of them, and I get the same results from my soldering lead, I’ve got 2 types, on is plain hard and the other one is a alloy with Tin to lower the melting point and it also stays cleaner for longer.

I’m also heavy into electronics.
 
  • #14
If you're mixing something, you'll need to tell us what you are doing because we can't guess. But elements do not transmute into other elements just by heating them. That's called alchemy and a lot of alchemists died trying to make that happen...
 
  • #15
Nope, I’m not mixing anything, just want to know why lead suddenly change to some weird burnout lead, it look like lead, but it’s strong in a way and brittle.
 
  • #16
It is obviously not lead... at least pure lead. It is very likely that the "pure" lead bars you "found" (?) are not pure lead but rather a lead alloy. The alloys give lead wetablity toward steel and copper (in electronics) and increase hardness. Changing the ratio of lead to alloying metal by removing some of the lead through volatilization could result in a hard, brittle alloy depending on the alloying metal(s). These alloying metals include one or more of the following: antimony, calcium, aluminum, barium, silver, tin, arsenic, strontium, indium, lithium, cadmium and copper.

Did the bars have any stamping identifiers? For example "L-52500".

You might want to test the residue futher.

The Merck Index has some tests that might help. I quote:

"Antimony - reacts with slight excess of HCl with aid of HNO3; Pour soln. in large vol of water; white ppt forms which becomes orange-red on addn of H2S and is sol in ammonium sulfide."

Under the same conditions, lead will be gray to black. A mixture of the two might look black, however.

You might try a flame test too. Read more here:

http://chemistry.about.com/library/weekly/aa110401a.htm

Antimony will have a green flame and lead a blue one. A mix will appear greenish. If it is contaminated with sodium, you won't see anything but yellow.
 
  • #17
At 1700C you're at the BP of most any high lead alloy.

jacques said:
Nope, I’m not mixing anything, just want to know why lead suddenly change to some weird burnout lead, it look like lead, but it’s strong in a way and brittle.
What is strong and brittle. If you cooled the melt back down, you might easily have a microstructure resembling some high temperature phase that is frozen in. This will depend on things like composition and cooling rate.

As of now, there are too many variables and unknowns in your experimental setup to say anything definite.

C-tree: Do you believe you can tell something of the order of 1% Sb from a flame color?
 
  • #18
Boiling point, lead is 1749C

I know this color flame tests, gold leaf makes a white flame then heated / melted, I look nice

This lead makes no color and no smell, it only changes from a silvery bubble to a suddenly a drop down and become red in color then further on heated, the color behaves like a heated piece of iron

I mostly cool down my metals in water and never melt it again.


Here’s another weird this somebody can hopefully answer:
If you heat a empty cola can with a heat source of ~1700C then you get some weird black skin falling of from the can surface, I’m not sure if it’s Teflon, all I know is that is a protective layer in the inside of the can, to stop the metal from rusting, HCL don’t eat is but the metal goes, it looks like transparent plastic, but if you heat it with ~1700C, it becomes black and can be picked up by a magnet?
 
  • #19
Gokul,

Nope! I also failed to realize that if any distillation occurred, it would be the antimony that would distill out first and a lead-enriched residue would result. By my logic, it should have been softer rather than harder...
 
  • #20
Jacquesl,

You have discovered the can liner. I'm sure that googling "steel can coating" will provide you an answer. The residue is interesting... Ferromagnetic?

Maybe you have discovered a "buckycan" form of carbon!
 
  • #21
Yip I know it’s a can liner. I did a Google about 2 weeks ago to check out, what the stuff is, but did not found usable info.

Maybe you have discovered a "buckycan" form of carbon!
Lol, I’m not that sure man, it’s probably old news in NASA. but if found anything usable about my “burned up can liner” please let me know?
 
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  • #22
Well, since you ask...

What if the carbon on the inside of the can (post heat treatment) is a form of activated carbon that contains magnetic particles. An understanding of the genesis of these magnetic particles might have some use. If the carbon can be used as a decolorizing carbon, filtration would not be required since a simple magnet could remove the spent decolorizing carbon. Speeds up continuous chemical production operations...

If the mechanism of the soot generation were understood, soot generation in diesel motors might be made to produce slightly magnetic particles which could be removed from the oil by a magnet thereby increasing the service life of the oil filter and lengthing the service interval between oil changes. This is BIG stuff for companies that operate large fleets of vechicles and would be totally great for the environment since oil spills or improper disposal of used oil would be minimized.

Good luck with it.

To get you started, iron compounds, regardless of oxidation state, might be reduced to a magnetite type material during combustion in the presence of excess carbon, the reducing agent in this case.
 
  • #23
It is not necessarily a ferromagnetic material. Paramagnetic materials are attracted to magnets as well. You might want to look up the magnetic susceptibility of some materials to find ones which would impart the properties you observed. Iron is a particularly strong one that is common. Copper is another.
 
  • #24
Should someone not be stepping in and saying "Jacquesl, wha the h*** are you doing playing with these things when you apparently don't have the expertise to do so. Among other dangers, the vapours off these things can be quite toxic. You could be poisoning yourself and possibly others."
 
  • #25
But what must the main purpose be, by making the soot/dirt, magnetic, to filter out the dirt/soot ?
I dint understand that picture so good yet

Dave, it’s not like I’m filling my room up with SO2 gasses, It’s just a can, man
 
  • #26
If you understood the process well enough, you could, for example, put an additive in diesel fuel that produced a magnetic soot particle. That particle would find its way into the oil and be removed by a magnet.

Activated carbon is difficult to remove by filtration and filter aid must be used. magnetic filtering would not require a filter or filter aid. There are many, many uses of magnetic activated carbon. Mercury removal in coal fired power plants, for example.
 
  • #27
Jacquesl said:
Dave, it’s not like I’m filling my room up with SO2 gasses, It’s just a can, man
I was concerned about lead vapour. The temps you're creating could liberate some elements that would normally be inert and harmless.
 
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  • #28
DaveC426913 said:
I was concerned about lead vapour. The temps you're creating could liberate some elements that would normally be inert and harmless.

I agree with Dave about the safety aspect, which should have been brought up early in this thread by the OP, IMO. "Using my exhaust hood, I noticed..."

This thread is close to being locked. Any last constuctive posts from y'all? o:)
 
  • #29
I also agree about the lead stuff. I didn’t know about lead vapor, will it be dangerous for people like me, then using “lead wire” I’m not sure what that called in Eng. It’s used to mount the parts with as soldier iron to the PC boards
 
  • #30
chemisttree said:
If you understood the process well enough, you could, for example, put an additive in diesel fuel that produced a magnetic soot particle. That particle would find its way into the oil and be removed by a magnet.

Activated carbon is difficult to remove by filtration and filter aid must be used. magnetic filtering would not require a filter or filter aid. There are many, many uses of magnetic activated carbon. Mercury removal in coal fired power plants, for example.

I don’t have a lot of experience with ICC engines, do you have a picture of that soot problem you’re talking about, and I don’t understand what the story with the soot is. I don’t know what soot is.
 
  • #31
chemisttree said:
If you got your "lead" from wheel weights or lead acid batteries, the hard brittle stuff left over when you distill out the lead is antimony. Antimony is hard, silver to gray and brittle. It will cause contact dermatitis, conjunctivitus (pink eye), nasal ulceration. Bad JU JU! Keep it away from any of your hydrogen experiments since it will form extremely toxic, volatile hydrides.

Find the Merck Index at your local College library and make friends with it.

Just a note... I hope that when you are doing this kind of stuff you aren't inhaling or you are using a good hood. A garage with a few open doors really won't cut it.

Berkeman,

This sounds like a warning to me! The can soot stuff is probably better on its own thread though.
 
  • #32
Just to add in, my burned up lead does not, have a silvery color, it’s more like gray. its just brittle, but not so hard and, the volume of the lead also stay the same and that's it!
I totally agree with you chemisttree, this tread can we gladly locked, for what I feel!
 

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