Using the Maxwell distribution laws to prove the collision flux equation

In summary, the integral is necessary in order to accurately calculate the collision flux of a gas through a given rectangular surface.
  • #1
Bipolarity
776
2
I have for a while been trying to understand the setup of this equation in calculating the collision flux of a gas through a given rectangular surface of area A:

Number of collisions in a time interval Δt is [itex] (\frac{N}{V})AΔt\int^{∞}_{0}v_{x}f(v_{x})dv_{x} [/itex] where [itex] f(v_{x}) [/itex] is the fraction of molecules with speed in the range [itex] (v_{x},v_{x}+dv_{x})[/itex].

My book explains it by asking to choose a particular velocity and consider the volume inhabited by all the particles which can make the collision however I don't understand why the integral comes in after that.

My book is Physical Chemistry for the Chemical and Biological Sciences by Raymond Chang

Perhaps someone can help me by offering insight into why the integral is done or break the reasoning down into simplier steps?

Thanks!

BiP
 
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  • #2
. The integral is necessary in order to calculate the total number of collisions in a given time interval. The integral essentially takes into consideration all possible velocities that the molecules may have, ranging from 0 to infinity. This is necessary in order to get an accurate estimate of the number of collisions in a given time interval. The equation essentially states that the number of collisions in a time interval Δt is equal to the number of particles per unit volume (\frac{N}{V}) times the area of the surface (A) times the time interval (Δt) times the integral of the speed distribution function (f(v_x)) between 0 and infinity. The speed distribution function essentially describes the fraction of molecules with a particular speed in the range (v_x, v_x+dv_x). The integral is necessary in order to take into account all possible velocities that the molecules may have. Thus, the integral essentially calculates the total number of collisions over a range of velocities, ranging from 0 to infinity.
 

What are the Maxwell distribution laws?

The Maxwell distribution laws describe the distribution of velocities for a gas at a given temperature. They state that the velocities of particles in a gas follow a bell-shaped curve, with the most probable velocity being the peak of the curve.

How do the Maxwell distribution laws relate to the collision flux equation?

The collision flux equation uses the Maxwell distribution laws to calculate the rate at which particles collide with a surface. This equation takes into account the number of particles with different velocities and their probability of colliding with the surface.

What is the significance of using the Maxwell distribution laws to prove the collision flux equation?

Using the Maxwell distribution laws to prove the collision flux equation allows us to accurately predict the rate of particle collisions with a surface. This is important in many scientific fields, such as chemistry and physics, where understanding particle interactions is crucial.

How are the Maxwell distribution laws experimentally verified?

The Maxwell distribution laws have been experimentally verified through various techniques, such as gas diffusion experiments and spectroscopic measurements. These experiments consistently show that the velocities of particles in a gas follow a bell-shaped curve, as predicted by the Maxwell distribution laws.

Can the Maxwell distribution laws be applied to all gases?

Yes, the Maxwell distribution laws can be applied to all gases, as long as the gas is in thermal equilibrium. This means that the gas particles have reached a stable temperature and are not undergoing any phase changes. Additionally, the Maxwell distribution laws are most accurate for gases that consist of non-interacting particles.

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