Can you help me draw multiple Lewis dot structures for ClO4-?

Lewis dot structures for an ion. One structure has already been provided and four more can be drawn by using double bonds instead of single, even though this may reduce stability. Linus Pauling's "dotted chemical bond" method can be used to solve the issue of having multiple mesomeric states for elements in their highest oxidation states.
  • #1
physicsss
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I'm asked to draw 5 possible lewis dot structures for this ion. But I can only think of one. which I 've attached here. I'm supposed to draw them and determine which is the most favorable. I know I can do that by calculating hte formal charges, but first I need to draw these structures. Any suggestions?
 

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  • #2
I can think of another 4 and it would be 6 altogether if you included the correct one...

Daniel.
 
  • #3
physicsss, the provided structure is usually referred to as a charged octet. By using double bonds instead of single, you can reduce the charge separation at the loss of an octet. There are several compounds which have non-octet structures so feel free to violate that rule (but realize that it comes at a cost, in terms of stability).
 
  • #4
Yes,most elements in their highest oxydation states will not obey the octet rule.Linus Pauling thought of a method of solving this problem of overabundence of mesomeric states by inventing the so-called "dotted chemical bond"...

Daniel.
 

1. What is the Lewis dot structure for ClO4-?

The Lewis dot structure for ClO4- is a central chlorine atom bonded to four oxygen atoms. Each oxygen atom has six dots around it, representing the six valence electrons, and the chlorine atom has two dots and a negative charge, representing its seven valence electrons.

2. How do you determine the total number of valence electrons in ClO4-?

To determine the total number of valence electrons in ClO4-, you count the valence electrons of each atom and add them together. Chlorine has 7 valence electrons and each oxygen has 6 valence electrons, giving a total of 7 + (4*6) = 31 valence electrons.

3. Why does the Lewis dot structure for ClO4- have a negative charge?

The Lewis dot structure for ClO4- has a negative charge because the molecule has gained an extra electron, giving it a total of 32 electrons. This extra electron is represented by the negative charge on the chlorine atom.

4. What is the hybridization of chlorine in the Lewis dot structure for ClO4-?

The hybridization of chlorine in the Lewis dot structure for ClO4- is sp3, meaning that it has four electron pairs around it and forms four single bonds with the oxygen atoms. This results in a tetrahedral arrangement of the atoms.

5. Why is the Lewis dot structure for ClO4- considered a stable molecule?

The Lewis dot structure for ClO4- is considered a stable molecule because all of the atoms in the molecule have a full octet of electrons. This means that they have achieved a more stable electron configuration, making the molecule less reactive and more stable.

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