Isobaric Process, finding Change in Internal Energy

In summary, assuming N2 is an ideal gas, the change in internal energy (ΔIE) of 7.57 moles of N2 gas heated isobarically from 18.6 oC to 50.9 oC is 3,049.29 Joules. However, the internal energy of ideal gases also includes the energy from rotation, so the actual internal energy is f/2 nRT, where f is the degrees of freedom (5 for a two-atomic molecule).
  • #1
yaylee
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Homework Statement



Assume nitrogen gas (N2) is an ideal gas. n = 7.57 moles of N2 gas are heated isobarically (at constant pressure) from temperature To = 18.6 oC to temperature Tf = 50.9 oC. Find:

c) ΔIE, the change in internal energy of the N2 gas

Homework Equations



Change in IE = Change in KE = (3/2)nRΔT

The Attempt at a Solution



Since this is an ideal gas, only Kinetic Energy considerations need to be accounted for, or,
Change in KE = Change in IE = (3/2)(7.57)(8.314)(50.9-18.6) = 3,049.29 Joules

Once again, thanks for the help! I think I am doing the correct thing, or am I going crazy? =)
 
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  • #2
The internal energy of the two-atomic ideal gas contains not only the translational KE, but also the energy connected to rotation. Generally, the internal energy of ideal gases is f/2 nRT where f is the degrees of freedom, 5 for a two-atomic molecule.

ehild
 
  • #3
(3/2)nRΔT accounts for only the change in translational KE of the molecules. N2 is not a monatomic gas, so the molecules can have additional motion besides translational motion.
 

1. What is an isobaric process?

An isobaric process is a thermodynamic process in which the pressure of a system remains constant while other parameters, such as volume and temperature, change. This means that the system is allowed to expand or contract while the pressure remains the same.

2. How is the change in internal energy calculated in an isobaric process?

The change in internal energy in an isobaric process can be calculated using the formula ΔU = nCpΔT, where ΔU is the change in internal energy, n is the number of moles of gas, Cp is the molar specific heat at constant pressure, and ΔT is the change in temperature.

3. Why is the change in internal energy different in an isobaric process compared to an isothermal process?

In an isobaric process, the change in internal energy is caused by both the change in temperature and the work done by the system. However, in an isothermal process, the temperature remains constant and therefore the change in internal energy is solely due to the work done by the system.

4. Can the change in internal energy be negative in an isobaric process?

Yes, the change in internal energy can be negative in an isobaric process. This indicates that the system has lost energy, either through work done by the system or heat transfer out of the system.

5. How does an isobaric process relate to real-life situations?

Isobaric processes are commonly seen in everyday situations, such as boiling water in an open pot or inflating a balloon. In these cases, the pressure remains constant while the temperature and volume change. Isobaric processes are also commonly used in industrial processes, such as in heat exchangers or gas turbines, where pressure needs to be maintained at a certain level.

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